Synthesis, structure, and reactivity of (C5H4SiMe3)2Y{(μ-FC6F4)(μ-Me)B(C6F5)2}:: Tight ion pairing in a cationic lanthanide complex

被引：60
|
作者：
Song, XJ [1 ]
Thornton-Pett, M [1 ]
Bochmann, M [1 ]
机构：
[1] Univ Leeds, Sch Chem, Leeds LS2 9TH, W Yorkshire, England
来源：
ORGANOMETALLICS | 1998年 / 17卷 / 06期
关键词：
D O I：
10.1021/om971044s
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The reaction of [Cp'2YMe](2) (Cp' = C5H5, C5H4SiMe3) with B(C6F5)(3) affords the complexes Cp'Y-2{MeB(C6F5)(3)}. The anion is coordinated in a chelating fashion via one ortho-fluorine atom and agostic interactions to two of the methyl hydrogens; the complexes are highly fluxional in solution. They act as initiators for the carbocationic polymerization of isobutene.
引用
收藏
页码：1004 / 1006
页数：3
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