One-step synthesis of ethyl acetate from ethene and oxygen

被引：4
|
作者：
Furuta, M [1 ]
Kung, MC [1 ]
Kung, HH [1 ]
机构：
[1] Northwestern Univ, Dept Chem Engn, Evanston, IL 60208 USA
来源：
APPLIED CATALYSIS A-GENERAL | 2000年 / 201卷 / 01期
关键词：
carboxylic acid esters; heteropoly acid; palladium; ethene oxidation;
D O I：
10.1016/S0926-860X(00)00553-6
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A one-step synthesis of ethyl acetate from a feed mixture of ethene, oxygen, and water using a supported Pd and silicotungstic acid catalyst was demonstrated. At about 180 degrees C and 25% ethene conversion, ethyl acetate could be produced with up to 46% selectivity, together with 34% acetic acid and ethanol that could be recycled. The catalyst was believed to be bifunctional, with Pd providing the oxidation function and the silicotungstic acid providing the acidic function. (C) 2000 Elsevier Science B.V. All rights reserved.
引用
收藏
页码：L9 / L11
页数：3
相关论文
共 50 条
  • [21] Synthesis of pogostone by one-step
    Chen, Han-Bin
    Zhou, Jiang-Tao
    Liu, Yu-Hong
    Zhang, Zhen-Biao
    Zhan, Ya-Xian
    Su, Zi-Ren
    Zeng, Hui-Fang
    JOURNAL OF ASIAN NATURAL PRODUCTS RESEARCH, 2017, 19 (02) : 172 - 175
  • [22] ONE-STEP SYNTHESIS OF (+/-)-FRONTALIN
    KONGKATHIP, N
    KONGKATHIP, B
    JOURNAL OF THE SCIENCE SOCIETY OF THAILAND, 1992, 18 (04): : 225 - 227
  • [23] One-step synthesis of isocorroles
    Nardis, Sara
    Pomarico, Giuseppe
    Fronczek, Frank R.
    Vicente, Maria Graca H.
    Paolesse, Roberto
    TETRAHEDRON LETTERS, 2007, 48 (49) : 8643 - 8646
  • [24] One-Step Synthesis of Normoftal
    A. N. Balaev
    E. V. Reshetnikov
    V. E. Fedorov
    Pharmaceutical Chemistry Journal, 2014, 48 : 49 - 50
  • [25] One-Step Synthesis of Normoftal
    Balaev, A. N.
    Reshetnikov, E. V.
    Fedorov, V. E.
    PHARMACEUTICAL CHEMISTRY JOURNAL, 2014, 48 (01) : 49 - 50
  • [26] ONE-STEP SYNTHESIS OF DODECAMETHYLCYCLOHEXASILANE
    LAGUERRE, M
    DUNOGUES, J
    CALAS, R
    JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1978, (06) : 272 - 272
  • [27] A ONE-STEP SYNTHESIS OF DIHYDROFLAVONOLS
    MULCHANDANI, NB
    CHADHA, MS
    CHEMISTRY & INDUSTRY, 1964, (36) : 1554 - 1554
  • [28] One-step synthesis of diphenyhnethanes
    Wei, QY
    Luo, YG
    Zhou, M
    Tao, FY
    Zhang, GL
    SYNTHETIC COMMUNICATIONS, 2005, 35 (06) : 835 - 843
  • [29] ONE-STEP SYNTHESIS OF CYCLOPENTADIENYLCHLOROSILANES
    KOSHUTIN, VI
    MAKSIMOVA, LN
    EMYASHEV, VI
    SMIRNOV, VA
    ZHURNAL OBSHCHEI KHIMII, 1976, 46 (01): : 146 - 150
  • [30] A one-step synthesis of tetrahydropyranopyranones from carbonyl compounds
    Armstrong, A
    Goldberg, FW
    Sandham, DA
    TETRAHEDRON LETTERS, 2001, 42 (27) : 4585 - 4587
12345