The effect of silica template structure on the pore structure of mesoporous carbons

被引:57
|
作者
Han, S [1 ]
Lee, KT [1 ]
Oh, SM [1 ]
Hyeon, T [1 ]
机构
[1] Seoul Natl Univ, Sch Chem Engn, Seoul 151744, South Korea
关键词
porous carbon; carbonization; BET surface area; electrochemical properties;
D O I
10.1016/S0008-6223(02)00439-6
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We have synthesized two kinds of mesoporous carbons using a spherical silica sol (SMC1 carbon) and an elongated silica sol (SMC3 carbon) as templates. Nitrogen isotherms and electrochemical experiments were performed to investigate the effect of the silica template structure on the pore structure of the resulting mesoporous carbons. When carbons produced using the same silica to resorcinol molar ratio were compared, both nitrogen isotherms and electrochemical studies revealed that the SMC3 carbons exhibit simpler pore connectivity than SMC1 carbons. (C) 2002 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:1049 / 1056
页数:8
相关论文
共 50 条
  • [31] Characterization of mesoporous carbons synthesized with SBA-16 silica template
    Kim, TW
    Ryoo, R
    Gierszal, KP
    Jaroniec, M
    Solovyov, LA
    Sakamoto, Y
    Terasaki, O
    JOURNAL OF MATERIALS CHEMISTRY, 2005, 15 (15) : 1560 - 1571
  • [32] Effect of pore structure on catalytic properties of mesoporous silica supported rhodium catalysts for the hydrogenation of cinnamaldehyde
    Shimizu, Taichi
    Ota, Masaki
    Sato, Yoshiyuki
    Inomata, Hiroshi
    CHEMICAL ENGINEERING RESEARCH & DESIGN, 2015, 104 : 174 - 179
  • [33] Effect of synthesis temperature on the ordered pore structure in mesoporous silica studied by positron annihilation spectroscopy
    Li, C. Y.
    Qi, N.
    Liu, Z. W.
    Zhou, B.
    Chen, Z. Q.
    Wang, Z.
    APPLIED SURFACE SCIENCE, 2016, 363 : 445 - 450
  • [34] Effect of inorganic salt addition during synthesis on pore structure and hydrothermal stability of mesoporous silica
    Yu, J
    Shi, JL
    Chen, HR
    Yan, JN
    Yan, DS
    MICROPOROUS AND MESOPOROUS MATERIALS, 2001, 46 (2-3) : 153 - 162
  • [35] Pore structure of carbon-mineral nanocomposites and derived carbons obtained by template carbonization
    Bandosz, TJ
    Jagiello, J
    Putyera, K
    Schwarz, JA
    CHEMISTRY OF MATERIALS, 1996, 8 (08) : 2023 - 2029
  • [36] Pore Structure of Carbon-Mineral Nanocomposites and Derived Carbons Obtained by Template Carbonization
    Bandosz, T. J.
    Jagiello, J.
    Putyera, K.
    Schwarz, J. A.
    Chemistry of Materials, 8 (08):
  • [37] Synthesis of mesoporous silica with controlled pore structure from bagasse ash as a silica source
    Rahman, Nanik Astuti
    Widhiana, Ika
    Juliastuti, Rachmania
    Setyawan, Heru
    COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2015, 476 : 1 - 7
  • [38] Synthesis of novel mesoporous silica spheres with starburst pore canal structure
    Zhang, YB
    Qian, XF
    Li, ZK
    Yin, J
    Zhu, ZK
    JOURNAL OF SOLID STATE CHEMISTRY, 2004, 177 (03) : 844 - 848
  • [39] Mechanism of regulating pore structure of polyethyleneimine modified mesoporous silica foam
    Wang Rong
    Yang Jing
    Zhang Tao
    Yu Run-Sheng
    Dong Jun-Cai
    Zhang Peng
    Cao Xing-Zhong
    Wang Bao -Yi
    Yin Hao
    ACTA PHYSICA SINICA, 2023, 72 (16)
  • [40] Study on Thermal Conductance in Bimodal-Pore Structure of Mesoporous Silica
    Wei, Gaosheng
    Huang, Chao
    Cui, Liu
    Du, Xiaoze
    Kung Cheng Je Wu Li Hsueh Pao/Journal of Engineering Thermophysics, 2023, 44 (02): : 517 - 524