Active species of molybdenum carbide catalysts in methane reforming:: η-Mo3C2

被引:5
|
作者
Oshikawa, K [1 ]
Nagai, M [1 ]
Omi, S [1 ]
机构
[1] Tokyo Univ Agr & Technol, Grad Sch Bioapplicat & Syst Engn, Koganei, Tokyo 1848588, Japan
关键词
D O I
10.1246/cl.2000.1086
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
eta-Mo3C2 was the most active molybdenum carbide species for-methane reforming, surpassing beta-Mo2C which has been reported previously. From the correlation of the TPR results, the amount of eta-Mo3C2 was directly related to the methane decomposition rate, indicating the importance of this type of carbide for methane reforming.
引用
收藏
页码:1086 / 1087
页数:2
相关论文
共 50 条
  • [21] Superconductivity in two-dimensional η-Mo3C2 films
    Shi, Wei
    Yu, Junyao
    Xu, Tao
    Liu, Weilin
    Huang, Xianlei
    Xu, Jie
    Sun, Litao
    Gao, Libo
    SCIENCE CHINA-MATERIALS, 2021, 64 (03) : 664 - 672
  • [22] Effect of molybdenum carbide concentration on the Ni/ZrO2 catalysts for steam-CO2 bi-reforming of methane
    Li, Weizuo
    Zhao, Zhongkui
    Ren, Panpan
    Wang, Guiru
    RSC ADVANCES, 2015, 5 (122): : 100865 - 100872
  • [23] In-situ synthesis of Ni-Mo2C/Al2O3 catalysts for dry reforming of methane
    Duan, Yiping
    Shang, Ruishu
    Zhong, Xinyan
    Xie, Wei
    Wang, Xingyue
    Huang, Lihong
    INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2016, 41 (47) : 21955 - 21964
  • [24] New bimetallic Mo2C-WC/Al2O3 membrane catalysts in the dry reforming of methane
    Kislov, V. R.
    Skudin, V. V.
    Adamu, A.
    KINETICS AND CATALYSIS, 2017, 58 (01) : 73 - 80
  • [25] Ni catalysts with Mo promoter for methane steam reforming
    Maluf, S. S.
    Assaf, E. M.
    FUEL, 2009, 88 (09) : 1547 - 1553
  • [26] New bimetallic Mo2C–WC/Al2O3 membrane catalysts in the dry reforming of methane
    V. R. Kislov
    V. V. Skudin
    A. Adamu
    Kinetics and Catalysis, 2017, 58 : 73 - 80
  • [27] Superconductivity in two-dimensional η-Mo3C2 films二维超导η-Mo3C2薄膜的可控制备
    Wei Shi
    Junyao Yu
    Tao Xu
    Weilin Liu
    Xianlei Huang
    Jie Xu
    Litao Sun
    Libo Gao
    Science China Materials, 2021, 64 : 664 - 672
  • [28] Molybdenum and nickel-molybdenum nitride catalysts supported on MgO-Al2O3 for the dry reforming of methane
    Aramouni, Nicolas Abdel Karim
    Zeaiter, Joseph
    Kwapinski, Witold
    Leahy, James J.
    Ahmad, Mohammad N.
    JOURNAL OF CO2 UTILIZATION, 2021, 44
  • [29] Effect of Carburization Conditions on the Activity of Molybdenum Carbide-Supported Catalysts Promoted by Nickel for the Dry Reforming of Methane
    Silva, Camila G.
    Passos, Fabio B.
    da Silva, Victor Teixeira
    ENERGY & FUELS, 2021, 35 (21) : 17833 - 17847
  • [30] Mo-Ni/Al2O3 catalysts for the methane steam reforming reaction
    Maluf, SS
    Assaf, EM
    Assaf, JM
    QUIMICA NOVA, 2003, 26 (02): : 181 - 187