Distinction between the weak hydrogen bond and the van der Waals interaction

被引：656

作者：

Steiner, T

Desiraju, GR

机构：

[1] Free Univ Berlin, Inst Kristallog, D-14195 Berlin, Germany

[2] Univ Hyderabad, Sch Chem, Hyderabad 500046, Andhra Pradesh, India

来源：

CHEMICAL COMMUNICATIONS | 1998年 / 08期

关键词：

D O I：

10.1039/a708099i

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The angular distributions of C-H ... O interactions for different types of C-H groups show that the directionality decreases with decreasing C-H polarisation, but that it is still clearly recognisable for methyl groups; for C-H ... H-C van der Waals contacts, in contrast, isotropic angular characteristics are observed.

引用

页码：891 / 892

页数：2

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