Fully inorganic cesium lead halide perovskites with improved stability for tandem solar cells

被引：0

作者：

Beal, Rachel E. ^{[1
]}

Slotcavage, Daniel J. ^{[1
]}

Leijtens, Tomas ^{[1
]}

Bowring, Andrea R. ^{[1
]}

Belisle, Rebecca A. ^{[1
]}

Nguyen, William H. ^{[1
]}

Burkhard, George F. ^{[1
]}

Hoke, Eric T. ^{[1
]}

McGehee, Michael D. ^{[1
]}

机构：

[1] Stanford Univ, Stanford, CA 94305 USA

来源：

2016 IEEE 43RD PHOTOVOLTAIC SPECIALISTS CONFERENCE (PVSC) | 2016年

关键词：

perovskites; thermal stability; tandems;

D O I：

暂无

中图分类号：

TE [石油、天然气工业]; TK [能源与动力工程];

学科分类号：

0807 ; 0820 ;

摘要：

A semiconductor that can be processed on a large scale with a bandgap around 1.8 eV could enable the manufacture of highly-efficient low cost double-junction solar cells. Solution-processable organic-inorganic halide perovskites have recently generated considerable excitement as absorbers in single-junction solar cells, and while it is possible to tune the bandgap of (CH3NH3)Pb(BrxI1-x)(3) between 2.3 and 1.6 eV by controlling the halide concentration, optical instability due to photo-induced phase segregation limits the voltage that can be extracted from compositions with appropriate bandgaps for tandem applications. Moreover, these materials have been shown to suffer from thermal degradation at temperatures within the processing and operational window. By replacing the volatile methylammonium cation with cesium, it is possible to synthesize a mixed halide absorber material with improved optical and thermal stability, a stabilized photoconversion efficiency of 6.5%, and a bandgap of 1.9 eV.

引用

页码：82 / 84

页数：3

共 50 条

[31] Surface Exciton Polariton in Cesium Lead Halide Perovskites
Hao, Jason
Owrutsky, Jeffrey
Ratchford, Daniel C.
Simpkins, Blake
Efros, Alexander L.
CHEMISTRY OF MATERIALS, 2025, 37 (06) : 2251 - 2257
[32] On constructing a dielectric function for cesium lead halide perovskites
Shabaev, A.
Jensen, K. L.
Lambrakos, S. G.
ALGORITHMS, TECHNOLOGIES, AND APPLICATIONS FOR MULTISPECTRAL AND HYPERSPECTRAL IMAGERY XXVI, 2020, 11392
[33] Intrinsic Carrier Mobility of Cesium Lead Halide Perovskites
Kang, Youngho
Han, Seungwu
PHYSICAL REVIEW APPLIED, 2018, 10 (04):
[34] Probing the Intrinsic Thermal and Photochemical Stability of Hybrid and Inorganic Lead Halide Perovskites
Akbulatov, Azat F.
Luchkin, Sergey Yu.
Frolova, Lyubov A.
Dremova, Nadezhda N.
Gerasimov, Kirill L.
Zhidkov, Ivan S.
Anokhin, Denis V.
Kurmaev, Ernst Z.
Stevenson, Keith J.
Troshin, Pavel A.
JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2017, 8 (06): : 1211 - 1218
[35] Computational high throughput screening of inorganic cation based halide perovskites for perovskite only tandem solar cells
Kar, M.
Koerzdoerfer, T.
MATERIALS RESEARCH EXPRESS, 2020, 7 (05)
[36] Addressing the Stability of Lead Halide Perovskites
Davies, Matthew L.
JOULE, 2020, 4 (08) : 1626 - 1627
[37] Wide-Bandgap Metal Halide Perovskites for Tandem Solar Cells
Tong, Jinhui
Jiang, Qi
Zhang, Fei
Kang, Seok Beom
Kim, Dong Hoe
Zhu, Kai
ACS ENERGY LETTERS, 2021, 6 (01): : 232 - 248
[38] All-inorganic halide perovskites as candidates for efficient solar cells
Zhang, Xie
Turiansky, Mark E.
Van de Walle, Chris G.
CELL REPORTS PHYSICAL SCIENCE, 2021, 2 (10):
[39] Light management in cesium lead halide/silicon tandem solar cells using periodic nanophotonic structure at front
Gupta, Nikhil Deep
OPTICAL ENGINEERING, 2020, 59 (12)
[40] Cesium Lead Mixed-Halide Perovskites for Low-Energy Loss Solar Cells with Efficiency Beyond 17%
Wang, Haoran
Bian, Hui
Jin, Zhiwen
Zhang, Hong
Liang, Lei
Wen, Jialun
Wang, Qian
Ding, Liming
Liu, Shengzhong Frank
CHEMISTRY OF MATERIALS, 2019, 31 (16) : 6231 - 6238

← 1 2 3 4 5 →