Unit-cell-level assembly of metastable transition-metal oxides by pulsed-laser deposition

被引:16
|
作者
Yan, Lei
Niu, Hongjun
Bridges, Craig A.
Marshall, Paul A.
Hadermann, Joke
van Tendeloo, Gustaav
Chalker, Paul R.
Rosseinsky, Matthew J.
机构
[1] Univ Liverpool, Dept Chem, Liverpool L69 7ZD, Merseyside, England
[2] Univ Liverpool, Dept Engn, Liverpool L69 7ZD, Merseyside, England
[3] Univ Antwerp, B-2020 Antwerp, Belgium
基金
英国工程与自然科学研究理事会;
关键词
electron microscopy; oxides; pulsed-laser deposition; Ruddlesden-Popper phases; thin films;
D O I
10.1002/anie.200700119
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
One layer at a time: The sequential pulsed-laser deposition of CaO rock-salt and CaMnO3 perovskite layers on an SrTiO3 substrate allows the growth of the metastable n = 4, 5, and 6 members of the Can+1MnnO3n+1 Ruddlesden-Popper series (see high-resolution TEM image of Ca5Mn4O13). The growth process is monitored using reflection high-energy electron diffraction. © 2007 Wiley-VCH Verlag GmbH &. Co. KGaA.
引用
收藏
页码:4539 / 4542
页数:4
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