Novel one-pot synthesis of aryltris(trimethylsilyl)silanes

被引:13
|
作者
Sanganee, MJ
Steel, PG
Whelligan, DK
机构
[1] Univ Durham, Dept Chem, Sci Labs, Durham DH1 3LE, England
[2] GlaxoSmithKline, Stevenage SG1 2NY, Herts, England
来源
JOURNAL OF ORGANIC CHEMISTRY | 2003年 / 68卷 / 08期
关键词
D O I
10.1021/jo0268660
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The simple combination of tris(trimethylsilyl)potassium, ArMgBr, and ArBr provides a novel "one-pot" synthesis of aryl(tristrimethylsilyl)silanes. A mechanistic rationale for this conversion is proposed.
引用
收藏
页码:3337 / 3339
页数:3
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