Synthesis and crystal structure of the oligomeric iodo-d10-metalates(II) [M(I)(CH3CN)4]4[Cd6I16].1.5CH3CN with M(I)=Cu, Li

被引：8

作者：

Bach, A ^{[1
]}

Hoyer, M ^{[1
]}

Hartl, H ^{[1
]}

机构：

[1] Free Univ Berlin, Inst Anorgan & Analyt Chem, D-14195 Berlin, Germany

来源：

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 1997年 / 52卷 / 12期

关键词：

iodocadmates; lithium iodocadmate; copper iodocadmate; crystal structure;

D O I：

10.1515/znb-1997-1210

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of CuI or MI with CdI2 in the polar solvent acetonitrile results in the formation of the iodocadmates [Cu(CH3CN)(4)](4)[Cd6I16] . 1.5CH(3)CN (1) and [Li(CH3CN)(4)](4)[Cd6I16] . 1.5CH(3)CN (2) with the oligomeric anion [Cd6I16](4-). This new type of halometallate anion, which is found in both isotypic structures, is built up by six alternating corner and edge sharing CdI4 tetrahedra. 1: Space group P (1) over bar (No 2), a = 838.5(4), b = 1465.9(9), c = 1929.8(6) pm, alpha = 93.01(3), beta = 99.13(3), gamma = 105.11(3)degrees; 1: Space group P (1) over bar (No 2), a = 841.7(8), b = 1470(9), c = 1945.5(9) pm, alpha = 93.27(5), beta = 99.13(5), gamma = 104.83(5)degrees.

引用

页码：1497 / 1500

页数：4

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