Synthesis and crystal structure of the oligomeric iodo-d10-metalates(II) [M(I)(CH3CN)4]4[Cd6I16].1.5CH3CN with M(I)=Cu, Li

被引：8
|
作者：
Bach, A [1 ]
Hoyer, M [1 ]
Hartl, H [1 ]
机构：
[1] Free Univ Berlin, Inst Anorgan & Analyt Chem, D-14195 Berlin, Germany
来源：
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 1997年 / 52卷 / 12期
关键词：
iodocadmates; lithium iodocadmate; copper iodocadmate; crystal structure;
D O I：
10.1515/znb-1997-1210
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The reaction of CuI or MI with CdI2 in the polar solvent acetonitrile results in the formation of the iodocadmates [Cu(CH3CN)(4)](4)[Cd6I16] . 1.5CH(3)CN (1) and [Li(CH3CN)(4)](4)[Cd6I16] . 1.5CH(3)CN (2) with the oligomeric anion [Cd6I16](4-). This new type of halometallate anion, which is found in both isotypic structures, is built up by six alternating corner and edge sharing CdI4 tetrahedra. 1: Space group P (1) over bar (No 2), a = 838.5(4), b = 1465.9(9), c = 1929.8(6) pm, alpha = 93.01(3), beta = 99.13(3), gamma = 105.11(3)degrees; 1: Space group P (1) over bar (No 2), a = 841.7(8), b = 1470(9), c = 1945.5(9) pm, alpha = 93.27(5), beta = 99.13(5), gamma = 104.83(5)degrees.
引用
收藏
页码：1497 / 1500
页数：4
相关论文
共 50 条
  • [1] Synthesis and Crystal Structures of Polyhalide Salts of Copper(I) Complexes [Cu(CH3CN)4]Br5 and [Cu(CH3CN)4]I5
    Usol'tsev, A. N.
    Korobeinikov, N. A.
    Sokolov, M. N.
    Adonin, S. A.
    RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2021, 66 (10) : 1477 - 1481
  • [2] Synthesis and Crystal Structures of Polyhalide Salts of Copper(I) Complexes [Cu(CH3CN)4]Br5 and [Cu(CH3CN)4]I5
    A. N. Usol’tsev
    N. A. Korobeinikov
    M. N. Sokolov
    S. A. Adonin
    Russian Journal of Inorganic Chemistry, 2021, 66 : 1477 - 1481
  • [3] CRYSTAL-STRUCTURE OF [CU4OCL6(CH3CN)4].2CH3CN
    HILLER, W
    ZINN, A
    DEHNICKE, K
    ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1990, 45 (11): : 1593 - 1596
  • [4] Synthesis of an unprecedented bicapped adamantold [CU6(μ2-I)(μ3-I)4(μ4-I)(m-tolyl3P)4(CH3CN)2] cluster
    Lobana, TS
    Kaur, P
    Nishioka, T
    INORGANIC CHEMISTRY, 2004, 43 (13) : 3766 - 3767
  • [5] Structure of (acetonitrile-N)copper(I) cyanide, [Cu(CH3CN)][CN]
    Keller, H. -L.
    Oldag, T.
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2006, 221 (03): : 377 - 378
  • [6] SYNTHESIS AND CRYSTAL-STRUCTURE OF [LI(12-CROWN-4)2][RECL5(CH3CN)].CH3CN
    STENGER, H
    WELLER, F
    DEHNICKE, K
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1991, 606 (15): : 109 - 117
  • [7] Synthesis and problematic crystal structures of [Al(CH3CN)(6)][MCl(6)](3)(CH3CN)(3) (M=Ta, Nb or Sb)
    BabianKibala, E
    Chen, H
    Cotton, FA
    Daniels, LM
    Falvello, LR
    Schmid, G
    Yao, ZG
    INORGANICA CHIMICA ACTA, 1996, 250 (1-2) : 359 - 364
  • [8] Crystal structures and vibrational spectroscopy of [NBu4][Cu(CN)X] (X = Br, I) and [NBu4[Cu3(CN)4]•CH3CN
    Bowmaker, GA
    Hartl, H
    Urban, V
    INORGANIC CHEMISTRY, 2000, 39 (20) : 4548 - 4554
  • [9] Synthesis and problematic crystal structures of [Al(CH3CN)6] [MCl6]3(CH3CN)3 (M = Ta, Nb or Sb)
    Department of Chemistry, Lab. for Molec. Struct. and Bonding, Texas A and M University, College Station, TX 77843, United States
    不详
    Inorg. Chim. Acta, 1-2 PART I (359-364):
  • [10] Synthesis and structure of acetonitrile solvates of copper(II) monofluoroacetate and silver(I) trifluoroacetate, [Cu2(CH2FCOO)4 • 2CH3CN](CH3CN) and Ag3(CF3COO)3(CH3CN)2
    Karpova, EV
    Boltalin, AI
    Korenev, YM
    Zakharov, MA
    Troyanov, SI
    RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2001, 27 (04) : 286 - 291
12345