Optimization of polymer electrolytes for quasi-solidstate dye-sensitized solar cells

被引:12
|
作者
Zhang, CN
Wang, M
Zhou, XM [1 ]
Lin, Y
Fang, SB
Li, XP
Xiao, XR
Cen, K
机构
[1] Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Key Lab Photochem, Beijing 100080, Peoples R China
[2] China Univ Geosci, Sch Earth Sci & Resources, Beijing 100083, Peoples R China
来源
CHINESE SCIENCE BULLETIN | 2004年 / 49卷 / 19期
基金
中国国家自然科学基金;
关键词
dye-sensitized solar cell; polymer electrolyte; nano-TiO2; particle; ionic liquid; ionic conductivity;
D O I
10.1360/03wb0227
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
The photoelectrochemical properties of the quasi-solid-state dye-sensitized solar cells based on polymer electrolytes consisting of polyethylene oxide (PEO) with the additions of nano-TiO2 and ionic liquid of MPII (1-methyl-3-propylimidazolium iodide) were studied. By using a composite polymer electrolyte of PEO : LiI : TiO2 : MPII : 12 = 3 : 3 : 3 : 7 : I (in mol ratio), the solar energy conversion efficiency of 3.2% under 100 mW-cm(-2) was obtained, which was 8 times higher than that of the cell using polymer electrolyte without any additives. The effect of the additives was attributed to the increase of ionic conductivity of the polymer electrolytes.
引用
收藏
页码:2033 / 2036
页数:4
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