A highly selective fluorescent 'turn-on' chemosensor for Zn2+ based on a benzothiazole conjugate: their applicability in live cell imaging and use of the resultant complex as a secondary sensor of CN-

被引:82
|
作者
Khairnar, Nilesh [1 ]
Tayade, Kundan [1 ]
Sahoo, Suban K. [2 ]
Bondhopadhyay, Banashree [3 ]
Basu, Anupam [3 ]
Singh, Jasminder [4 ]
Singh, Narinder [4 ]
Gite, Vikas [1 ]
Kuwar, Anil [1 ]
机构
[1] North Maharashtra Univ, Sch Chem Sci, Jalgaon 425001, MS, India
[2] SV Natl Inst Technol, Dept Appl Chem, Surat 395007, India
[3] Univ Burdwan, Dept Zool, Mol Biol & Human Genet Lab, Burdwan 713104, W Bengal, India
[4] Indian Inst Technol, Dept Chem, Ropar 140001, Panjab, India
关键词
ZINC; RECOGNITION; RECEPTOR;
D O I
10.1039/c4dt03247k
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
A benzothiazole derivative linked "off-on" multi-responsive and selective chemosensor 3 has been synthesized and evaluated for cation recognition properties. The receptor 3 shows a high sensitivity and selectivity for Zn2+ through a 'turn-on' fluorescence response over the other tested cations with a detection limit as low as 0.67 mu M. The receptor 3 was successfully applied for the detection of Zn2+ in live HeLa cells. Then, the Zn2+ complex of receptor 3 was also used for cyanide detection and recognition.
引用
收藏
页码:2097 / 2102
页数:6
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