Asymmetric ring opening of epoxides

被引：146
|
作者：
Pastor, IM
Yus, M
机构：
[1] Univ Alicante, Fac Ciencias, Dept Quim Organ, E-03080 Alicante, Spain
[2] Univ Alicante, ISO, E-03080 Alicante, Spain
来源：
CURRENT ORGANIC CHEMISTRY | 2005年 / 9卷 / 01期
关键词：
D O I：
10.2174/1385272053369385
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
This review deals with the metal promoted asymmetric ring opening of achiral epoxides using achiral carbon-, nitrogen-, oxygen-, sulphur- and halogen-containing nucleophiles. The use of chiral bases in the asymmetric deprotonation of achiral epoxides yields chiral allylic alcohols. Finally, kinetic resolution of racemic epoxides can be achieved using chiral metal complexes.
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页码：1 / 29
页数：29
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