Asymmetric Ring-Opening of Epoxides Catalyzed by Metal-Salen Complexes

被引：24
|
作者：
Lidskog, Anna [1 ]
Li, Yutang [1 ]
Warnmark, Kenneth [1 ]
机构：
[1] Lund Univ, Ctr Anal & Synth, POB 124, SE-22100 Lund, Sweden
来源：
CATALYSTS | 2020年 / 10卷 / 06期
基金：
瑞典研究理事会;
关键词：
asymmetric catalysis; salen complexes; ring-opening; epoxide; kinetic resolution; HYDROLYTIC KINETIC RESOLUTION; HIGHLY ENANTIOSELECTIVE RESOLUTION; POLYMERIC CO(III)-SALEN COMPLEXES; OLIGOMERIC (SALEN)CO CATALYST; ALPHA-ARYLOXY ALCOHOLS; SCHIFF-BASE COMPLEXES; TERMINAL EPOXIDES; MESO-EPOXIDES; RACEMIC EPOXIDES; COOPERATIVE ACTIVATION;
D O I：
10.3390/catal10060705
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The asymmetric ring-opening of epoxides is an important reaction in organic synthesis, since it allows for the enantioselective installation of two vicinal functional groups with specific stereochemistry within one step from a highly available starting material. An effective class of catalysts for the asymmetric ring-opening of epoxides is metal-salen complexes. This review summarizes the development of metal-salen catalyzed enantioselective desymmetrization ofmeso-epoxides and kinetic resolution of epoxides with various nucleophiles, including the design and application of both homogeneous- and heterogeneous epoxide-opening catalysts as well as multi-metallic covalent and supramolecular catalytic systems.
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页数：65
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