Rotationally resolved photoelectron study of O2:: Identification of the vibrational progressions for O2+(22Πu,2Σu-) at 19.6-21.0 eV

被引：14
|
作者：
Hsu, CW
Evans, M
Stimson, S
Ng, CY [1 ]
机构：
[1] US DOE, Ames Lab, Ames, IA 50011 USA
[2] Univ Calif Berkeley, Lawrence Berkeley Lab, Div Chem Sci, Berkeley, CA 94720 USA
[3] Iowa State Univ Sci & Technol, Dept Chem, Ames, IA 50011 USA
来源：
JOURNAL OF CHEMICAL PHYSICS | 1998年 / 108卷 / 12期
关键词：
D O I：
10.1063/1.475920
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
On the basis of rotationally resolved pulsed field ionization photoelectron measurements, we have shown that the weak vibrational progressions in the energy region of 19.6-21.0 eV observed in recent high resolution photoelectron spectroscopic studies of O-2 are associated with transitions to the 2 (2) Pi(u 1/2) (2 (2) Pi(u 3/2)) and 2 Sigma(u)(-)states of O-2(+), with ionization energies of 19.6268+/-0.0005 eV (19.6329+/-0.0005 eV) and 20.3528+/-0.0005 eV, respectively. (C) 1998 American Institute of Physics.
引用
收藏
页码：4701 / 4704
页数：4
相关论文
共 50 条
  • [31] REDISTRIBUTION UNDER THERMAL-GRADIENT OF CATIONS IN MIXED (U,CE)O2 AND (U,PU)O2 CATIONS
    BAPTISTE, PJ
    JOURNAL OF NUCLEAR MATERIALS, 1984, 120 (2-3) : 316 - 341
  • [32] Ab initio calculation of the potential curve of B3Σu- state of O2
    Li Chen-Xi
    Guo Ying-Chun
    Wang Bing-Bing
    ACTA PHYSICA SINICA, 2017, 66 (10)
  • [33] λ and γ reversal:: The dissociation-limit region of the B3Σu- state of O2
    Waring, K
    Lewis, BR
    Baldwin, KGH
    Gibson, ST
    JOURNAL OF CHEMICAL PHYSICS, 2001, 115 (13): : 5836 - 5842
  • [34] Rotationally resolved absorption spectrum of the O2 dimer in the visible range
    Campargue, A
    Biennier, L
    Kachanov, A
    Jost, R
    Bussery-Honvault, B
    Veyret, V
    Churassy, S
    Bacis, R
    CHEMICAL PHYSICS LETTERS, 1998, 288 (5-6) : 734 - 742
  • [35] Melting behavior of (Th,U)O2 and (Th,Pu)O2 mixed oxides
    Ghosh, P. S.
    Kuganathan, N.
    Galvin, C. O. T.
    Arya, A.
    Dey, G. K.
    Dutta, B. K.
    Grimes, R. W.
    JOURNAL OF NUCLEAR MATERIALS, 2016, 479 : 112 - 122
  • [36] Competition between autoionization and dissociation in the [O2+(B 2Σg-)]nl and [O2+(c 4Σu-)]nl Rydberg states investigated by photon-induced dissociation to neutral fragments
    Hikosaka, Y
    Lablanquie, P
    Ahmad, M
    Hall, RI
    Lambourne, JG
    Penent, F
    Eland, JHD
    JOURNAL OF PHYSICS B-ATOMIC MOLECULAR AND OPTICAL PHYSICS, 2003, 36 (21) : 4311 - 4326
  • [37] 2ND SIGMA-3(U-) STATE OF O-2
    YOSHIMINE, M
    TANAKA, K
    TATEWAKI, H
    OBARA, S
    SASAKI, F
    OHNO, K
    JOURNAL OF CHEMICAL PHYSICS, 1976, 64 (05): : 2254 - 2255
  • [38] CONVERSION OF (TH,U)O2 FUEL TO (TH,U)C2 FOR REPROCESSING
    CARLSON, ON
    CHIOTTI, P
    TRANSACTIONS OF THE AMERICAN NUCLEAR SOCIETY, 1978, 28 (JUN): : 163 - 164
  • [39] Non-Franck-Condon effects in the photoionization of N2 to the N2+ A 2Πu state and of O2 to the O2+ X 2Πg state in the 19-34 eV photon energy region
    Rius, J
    Riu, I
    Alvarez, J
    Karawajczyk, A
    Stankiewicz, M
    Winiarczyk, P
    Veseth, L
    SURFACE REVIEW AND LETTERS, 2002, 9 (01) : 147 - 152
  • [40] DRIFT TUBE MEASUREMENTS OF - REACTIONS U+ + O2 AND U+ + N2 FROM THERMAL ENERGY TO 11 EV
    JOHNSEN, R
    BIONDI, MA
    BULLETIN OF THE AMERICAN PHYSICAL SOCIETY, 1972, 17 (03): : 402 - &
12345