Unexpected formation of 1,4-diphenylbutylphosphinic acid from 1,4-diphenylbuta-1,3-diene and elemental phosphorus via the Trofimov-Gusarova reaction

被引：8

作者：

Artem'ev, Alexander V. ^{[1
]}

Sutyrina, Anastasiya O. ^{[2
]}

Matveeva, Elena A. ^{[2
]}

Albanov, Alexander I. ^{[2
]}

Klyba, Lyudmila V. ^{[2
]}

机构：

[1] Russian Acad Sci, Siberian Branch, AV Nikolaev Inst Inorgan Chem, Novosibirsk 630090, Russia

[2] Russian Acad Sci, Siberian Branch, AE Favorsky Irkutsk Inst Chem, Irkutsk 664033, Russia

来源：

MENDELEEV COMMUNICATIONS | 2017年 / 27卷 / 02期

关键词：

WHITE PHOSPHORUS; FUNCTIONALIZATION; CHEMISTRY;

D O I：

10.1016/j.mencom.2017.03.009

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

trans,trans-1,4-Diphenylbuta-1,3-diene reacts with elemental (red) phosphorus in the superbasic KOH/DMSO (H2O) system (120 degrees C, 3 h) to give, after acidic work-up, 1,4-di-phenylbutylphosphinic acid in 48% yield.

引用

页码：137 / 138

页数：2

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