Self-Assembly of Triphenylamine Macrocycles and Co-assembly with Guest Molecules at the Liquid-Solid Interface Studied by STM: Influence of Different Side Chains on Host-Guest Interaction

被引：10
|
作者：
Meng, Ting [1 ,2 ,3 ]
Lu, Yingbo [4 ]
Lei, Peng [1 ,2 ]
Li, Shijun [5 ]
Deng, Ke [1 ,2 ]
Xiao, Xunwen [3 ]
Ogino, Kenji [4 ]
Zeng, Qingdao [1 ,2 ]
机构：
[1] Natl Ctr Nanosci & Technol NCNST, CAS Ctr Excellence Nanosci, CAS Key Lab Standardizat & Measurement Nanotechno, Beijing 100190, Peoples R China
[2] Univ Chinese Acad Sci, Ctr Mat Sci & Optoelect Engn, Beijing 100049, Peoples R China
[3] Ningbo Univ Technol, Sch Mat & Chem Engn, Ningbo 315211, Peoples R China
[4] Tokyo Univ Agr & Technol, Grad Sch Bioapplicat & Syst Engn, Koganei, Tokyo 1848588, Japan
[5] Hangzhou Normal Univ, Coll Mat Chem & Chem Engn, Hangzhou 311121, Peoples R China
来源：
LANGMUIR | 2022年 / 38卷 / 11期
基金：
中国国家自然科学基金; 美国国家科学基金会;
关键词：
STRUCTURAL TRANSFORMATION; ADSORPTION BEHAVIORS; PEROVSKITE; CHEMISTRY; NETWORKS;
D O I：
10.1021/acs.langmuir.2c00188
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The side chains of macrocyclic molecules have a non-negligible effect on the two-dimensional (2D) supramolecular networks at the liquid-solid interface. In this study, we investigate the self-assembly behaviors of two conjugated triphenylamine macrocycles modified with different alkyl chains and construct the host-guest supramolecular nanopatterns on the highlyoriented pyrolytic graphite with a scanning tunneling microscope. Incombination with density functional theory calculations, how different sidechains affect the host-guest interaction is discussed. This work provides insights into constructing a 2D host-guest dynamic co-assembly on the surface
引用
收藏
页码：3568 / 3574
页数：7
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