Enantioselective synthesis of α-alkyl-β,γ-unsaturated esters through efficient Cu-catalyzed allylic alkylations

被引：92
|
作者：
Murphy, KE [1 ]
Hoveyda, AH [1 ]
机构：
[1] Boston Coll, Dept Chem, Merkert Chem Ctr, Chestnut Hill, MA 02467 USA
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2003年 / 125卷 / 16期
关键词：
D O I：
10.1021/ja0300618
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
引用
收藏
页码：4690 / 4691
页数：2
相关论文
共 50 条
  • [21] Enantioselective Synthesis of Boryl Tetrahydroquinolines via Cu-Catalyzed Hydroboration
    Kong, Duanyang
    Han, Suna
    Zi, Guofu
    Hou, Guohua
    Zhang, Jiaxin
    JOURNAL OF ORGANIC CHEMISTRY, 2018, 83 (04): : 1924 - 1932
  • [22] Enantioselective Synthesis of α-Alkyl-β-ketoesters: Asymmetric Roskamp Reaction Catalyzed by an Oxazaborolidinium Ion
    Gao, Lizhu
    Kang, Byung Chul
    Hwang, Geum-Sook
    Ryu, Do Hyun
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2012, 51 (33) : 8322 - 8325
  • [23] Cu-catalyzed enantioselective conjugate additions of alkyl zinc reagents to unsaturated N-acyloxazolidinones promoted by a chiral triamide phosphane
    Hird, AW
    Hoveyda, AH
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (11) : 1276 - 1279
  • [24] Cu-Catalyzed Carbonylative Silylation of Alkyl Halides: Efficient Access to Acylsilanes
    Cheng, Li-Jie
    Mankad, Neal P.
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2020, 142 (01) : 80 - 84
  • [25] Cu-Catalyzed Direct Enantioselective Vinylogous Mannich Reaction between β,γ-Unsaturated Pyrazoleamides and Ketimines
    Luo, Ling-Shan
    Hou, Si-Meng
    Lu, Jian
    Zhang, Qi
    Sha, Feng
    Wu, Xin-Yan
    JOURNAL OF ORGANIC CHEMISTRY, 2024, 89 (04): : 2582 - 2587
  • [26] Development of enantioselective Cu-catalyzed allylic oxidation reactions with N-heterocyclic carbene ligands
    Morrison, Ryan J.
    Khubchandani, Nisha A.
    Lombardi, Pamela J.
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2014, 247
  • [27] Efficient Preparation of β-Branched γ,δ-Unsaturated Esters through Copper-Catalyzed Allylic Alkylation of Ketene Silyl Acetal
    Li, Dong
    Ohmiya, Hirohisa
    Sawamura, Masaya
    SYNTHESIS-STUTTGART, 2012, 44 (09): : 1304 - 1307
  • [28] Enantioselective synthesis of acyclic allylic esters catalyzed by a palladium/BINAP(S) system
    Faller, JW
    Wilt, JC
    TETRAHEDRON LETTERS, 2004, 45 (41) : 7613 - 7616
  • [29] Aminoalcohol Synthesis through Nonprecious Metal Catalysis: Enantioselective Cu-Catalyzed Reductive Coupling of Aldehydes and Allenamides
    Klake, Raphael K.
    Sieber, Joshua D.
    ORGANIC LETTERS, 2023, 25 (25) : 4730 - 4734
  • [30] Synthesis of 1,2-Aminoalcohols through Enantioselective Aminoallylation of Ketones by Cu-Catalyzed Reductive Coupling
    Klake, Raphael K.
    Edwards, Mytia D.
    Sieber, Joshua D.
    ORGANIC LETTERS, 2021, 23 (16) : 6444 - 6449
12345