Enantioselective synthesis of α-alkyl-β,γ-unsaturated esters through efficient Cu-catalyzed allylic alkylations

被引:92
|
作者
Murphy, KE [1 ]
Hoveyda, AH [1 ]
机构
[1] Boston Coll, Dept Chem, Merkert Chem Ctr, Chestnut Hill, MA 02467 USA
关键词
D O I
10.1021/ja0300618
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
引用
收藏
页码:4690 / 4691
页数:2
相关论文
共 50 条
  • [2] Catalytic enantioselective synthesis of quaternary all-carbon stereogenic centers.: Preparation of α,α'-disubstituted β,γ-unsaturated esters through Cu-catalyzed asymmetric allylic alkylations
    Murphy, KE
    Hoveyda, AH
    ORGANIC LETTERS, 2005, 7 (07) : 1255 - 1258
  • [3] Enantioselective synthesis of allylsilanes bearing tertiary and quaternary Si-substituted carbons through Cu-catalyzed allylic Alkylations with alkylzinc and arylzinc reagents
    Kacprzynski, Monica A.
    May, Tricia L.
    Kazane, Stephanie A.
    Hoveyda, Amir H.
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, 46 (24) : 4554 - 4558
  • [4] Cu-catalyzed enantioselective allylic alkylation with organolithium reagents
    Valentín Hornillos
    Sureshbabu Guduguntla
    Martín Fañanás-Mastral
    Manuel Pérez
    Pieter H Bos
    Alena Rudolph
    Syuzanna R Harutyunyan
    Ben L Feringa
    Nature Protocols, 2017, 12 : 493 - 505
  • [5] Cu-catalyzed enantioselective allylic alkylation with organolithium reagents
    Hornillos, Valentin
    Guduguntla, Sureshbabu
    Fananas-Mastral, Martin
    Perez, Manuel
    Bos, Pieter H.
    Rudolph, Alena
    Harutyunyan, Syuzanna R.
    Feringa, Ben L.
    NATURE PROTOCOLS, 2017, 12 (03) : 493 - 505
  • [6] Synthesis of Quaternary Carbon Stereogenic Centers through Enantioselective Cu-Catalyzed Allylic Substitutions with Vinylaluminum Reagents
    Gao, Fang
    McGrath, Kevin P.
    Lee, Yunmi
    Hoveyda, Amir H.
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (40) : 14315 - 14320
  • [7] Synthesis of β-Silyl-α-amino Acid Derivatives by Cu-Catalyzed Regio- and Enantioselective Silylamination of α,β-Unsaturated Esters
    Kobayashi, Toshimichi
    Nishino, Soshi
    Miura, Masahiro
    Hirano, Koji
    ORGANIC LETTERS, 2022, 24 (06) : 1418 - 1422
  • [8] Cu-catalyzed enantioselective assembly of axially chiral allylic boronates
    Wang, Shuai
    Liu, Jianbo
    Ma, Wenyue
    Song, Qiuling
    SCIENCE CHINA-CHEMISTRY, 2024,
  • [10] Bidentate NHC-based chiral ligands for efficient Cu-catalyzed enantioselective allylic alkylations: Structure and activity of an air-stable chiral Cu complex
    Larsen, AO
    Leu, W
    Oberhuber, CN
    Campbell, JE
    Hoveyda, AH
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (36) : 11130 - 11131