THERMODYNAMIC PROPERTIES OF Co-Pr ALLOYS

被引：1
|
作者：
Sudavtsova, V. S. [1 ]
Shevchenko, M. O. [1 ]
Kudin, V. G. [2 ]
Romanova, L. O. [1 ]
Ivanov, M. I. [1 ]
机构：
[1] Natl Acad Sci Ukraine, Frantsevich Inst Problems Mat Sci, Kiev, Ukraine
[2] Taras Shevchenko Natl Univ, Kiev, Ukraine
来源：
POWDER METALLURGY AND METAL CERAMICS | 2017年 / 56卷 / 1-2期
关键词：
thermodynamic properties; cobalt; praseodymium; calorimetry;
D O I：
10.1007/s11106-017-9876-6
中图分类号：
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号：
0805 ; 080502 ;
摘要：
The mixing enthalpies of the Co-Pr liquid binary alloys are determined by isoperibol calorimetry in the composition ranges 0 < x(Pr) < 0.23 and 0.4 < x(Pr) < 1 at 1500-1820 K. The thermodynamic properties of the Co-Pr liquid binary alloys are calculated for the entire composition range using the model of ideal associated solutions. The thermodynamic activities of components show negative deviations from the ideal behavior; the mixing enthalpies are characterized by moderate exothermic effects. The minimum mixing enthalpy of melts is -12.0 kJ/mol at x(Pr) = 0.46.
引用
收藏
页码：94 / 101
页数：8
相关论文
共 50 条
  • [31] Thermodynamic Properties of Eu–In Alloys
    V. V. Berezutskii
    M. I. Ivanov
    M. O. Shevchenko
    V. S. Sudavtsova
    Powder Metallurgy and Metal Ceramics, 2015, 53 : 693 - 700
  • [32] THERMODYNAMIC PROPERTIES OF GALLIUM ALLOYS
    PREDEL, B
    JOURNAL DE CHIMIE PHYSIQUE ET DE PHYSICO-CHIMIE BIOLOGIQUE, 1977, 74 (7-8) : 827 - 835
  • [33] Effect of hot deformation on texture and magnetic properties of Sm-Co and Pr-Co alloys
    Gabay, A. M.
    Li, W. F.
    Hadjipanayis, G. C.
    JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS, 2011, 323 (20) : 2470 - 2473
  • [34] THERMODYNAMIC PROPERTIES OF CO
    BIOLSI, L
    PHAIR, R
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1989, 197 : 52 - PHYS
  • [35] STRUCTURE AND PHASE COMPOSITION OF ALLOYS PR(CO, CU)5, PR(CO, CU, FE)5 AND PR(CO, NI)5
    ZAKHAROV.MI
    FUENTES, K
    FIZIKA METALLOV I METALLOVEDENIE, 1973, 36 (03): : 662 - 664
  • [36] Chemical partitioning for the Co-Pr system: First-principles, experiments and energetic calculations to investigate the hard magnetic phase
    Zhou, S. H.
    Kramer, M. J.
    Meng, F. Q.
    McCallum, R. W.
    Ott, R. T.
    MATERIALS & DESIGN, 2016, 90 : 991 - 1004
  • [37] A METHOD FOR INVESTIGATION OF THERMODYNAMIC PROPERTIES OF ALLOYS
    ALEKSEEV, VI
    SUROVOI, YN
    INDUSTRIAL LABORATORY, 1965, 31 (11): : 1696 - &
  • [38] THERMODYNAMIC PROPERTIES OF MANGANESE AND PALLADIUM ALLOYS
    SIROTA, NN
    ORLIK, LK
    DOKLADY AKADEMII NAUK SSSR, 1973, 213 (05): : 1065 - 1067
  • [39] THERMODYNAMIC PROPERTIES OF LIQUID LITHIUM ALLOYS
    MORACHEVSKII, AG
    DEMIDOV, AI
    ZHURNAL FIZICHESKOI KHIMII, 1983, 57 (09): : 2113 - 2128
  • [40] Thermodynamic Properties of Ni–Sb Alloys
    K. Yu. Pastushenko
    V. S. Sudavtsova
    P. P. Levchenko
    M. A. Shevchenko
    M. I. Ivanov
    Powder Metallurgy and Metal Ceramics, 2019, 58 : 222 - 229
12345