Direct Catalytic Olefination of Alcohols with Sulfones

被引：64

作者：

Srimani, Dipankar ^{[1
]}

Leitus, Gregory ^{[2
]}

Ben-David, Yehoshoa ^{[1
]}

Milstein, David ^{[1
]}

机构：

[1] Weizmann Inst Sci, Dept Organ Chem, IL-76100 Rehovot, Israel

[2] Weizmann Inst Sci, IL-76100 Rehovot, Israel

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2014年 / 53卷 / 41期

基金：

欧洲研究理事会; 以色列科学基金会;

关键词：

homogeneous catalysis; olefination; pincer complexes; ruthenium; stilbenes; STEREOSELECTIVE-SYNTHESIS; OXIDATION; CARBANIONS; ACTIVATION; CONVENIENT; EFFICIENT; SYSTEM;

D O I：

10.1002/anie.201407281

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The synthesis of terminal, as well as internal, olefins was achieved by the one-step olefination of alcohols with sulfones catalyzed by a ruthenium pincer complex. Furthermore, performing the reaction with dimethyl sulfone under mild hydrogen pressure provides a direct route for the replacement of alcohol hydroxy groups by methyl groups in one step.

引用

页码：11092 / 11095

页数：4

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