Cleavage of the carbon-carbon bond in biphenylene using transition metals

被引：141

作者：

Perthuisot, C ^{[1
]}

Edelbach, BL ^{[1
]}

Zubris, DL ^{[1
]}

Simhai, N ^{[1
]}

Iverson, CN ^{[1
]}

Müller, C ^{[1
]}

Satoh, T ^{[1
]}

Jones, WD ^{[1
]}

机构：

[1] Univ Rochester, Dept Chem, Rochester, NY 14627 USA

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 2002年 / 189卷 / 01期

关键词：

C-C bond cleavage; oxidative addition; functionalization; catalysis;

D O I：

10.1016/S1381-1169(02)00203-0

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Biphenylene has proven to have a rich chemistry with transition metals. In many cases, the aryl-aryl C-C bond is cleaved to give a metallocycle complex, which can go on to give a variety of reaction products. Insertion reactions with small molecules lead to the formation of new polycyclic aromatic derivatives with the incorporation of functional groups. In several cases, these reactions are selective and catalytic. (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：157 / 168

页数：12

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