Gas permeation and selectivity characteristics of PSf based nanocomposite membranes

被引:16
|
作者
Swain, Suchhanda S. [1 ]
Unnikrishnan, Lakshmi [1 ]
Mohanty, Smita [1 ]
Nayak, Sanjay K. [1 ]
机构
[1] CIPET, SARP, LARPM, B-25,CNI Complex, Bhubaneswar 751024, Odisha, India
关键词
High-performance gas separation MMMs; Hybrid graphene nanosheets; Improved mechanical strength; Excellent ideal selectivity factor; MIXED-MATRIX MEMBRANES; GRAPHENE-OXIDE NANOSHEETS; THIN-FILM COMPOSITE; MECHANICAL-PROPERTIES; THERMAL-PROPERTIES; SALT REJECTION; SILICA; SEPARATION; POLYSULFONE; NANOPARTICLES;
D O I
10.1016/j.polymer.2019.121692
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
This study highlights successful development and evaluates the characteristics of graphene-derived nanohybrids (SGO and RSGO) incorporated MMM systems. Pristine GO and modified SiO2 (mSiO(2)) based membranes have also been prepared to assay the established synergistic effect on the performance. FTIR and WCA studies were carried out to endorse the insertion of different nanofillers into the virgin PSf matrix. SEM with EDS and AFM were accomplished to substantiate the distribution and dispersion pattern of the fillers within the base matrix. From the mechanical analysis, 46% improved tensile strength was perceived for the hybrid MMM system containing SGO. Finally, the dexterity was documented by analyzing the permeation behavior of the prepared membranes towards the selected O-2/N-2 gas pair. The hybrid PSf/SGO system displayed 605% and 801% higher permeabilities for O-2 as compared to the parent counterparts: (PSf/mSiO(2), PSf/GO), respectively. Meanwhile, PSf/RSGO membrane exhibited a slightly reduced performance than the former hybrid system.
引用
收藏
页数:14
相关论文
共 50 条
  • [21] Gas permeation through graphdiyne-based nanoporous membranes
    Zhou, Zhihua
    Tan, Yongtao
    Yang, Qian
    Bera, Achintya
    Xiong, Zecheng
    Yagmurcukardes, Mehmet
    Kim, Minsoo
    Zou, Yichao
    Wang, Guanghua
    Mishchenko, Artem
    Timokhin, Ivan
    Wang, Canbin
    Wang, Hao
    Yang, Chongyang
    Lu, Yizhen
    Boya, Radha
    Liao, Honggang
    Haigh, Sarah
    Liu, Huibiao
    Peeters, Francois M.
    Li, Yuliang
    Geim, Andre K.
    Hu, Sheng
    NATURE COMMUNICATIONS, 2022, 13 (01)
  • [22] Gas permeation through graphdiyne-based nanoporous membranes
    Zhihua Zhou
    Yongtao Tan
    Qian Yang
    Achintya Bera
    Zecheng Xiong
    Mehmet Yagmurcukardes
    Minsoo Kim
    Yichao Zou
    Guanghua Wang
    Artem Mishchenko
    Ivan Timokhin
    Canbin Wang
    Hao Wang
    Chongyang Yang
    Yizhen Lu
    Radha Boya
    Honggang Liao
    Sarah Haigh
    Huibiao Liu
    Francois M. Peeters
    Yuliang Li
    Andre K. Geim
    Sheng Hu
    Nature Communications, 13
  • [23] Mixed-Gas Selectivity Based on Pure Gas Permeation Measurements: An Approximate Model
    Malakhov, Alexander O.
    Volkov, Vladimir V.
    MEMBRANES, 2021, 11 (11)
  • [24] ZIF-8 @polycarbonate nanocomposite membranes for improved permeability and selectivity for hydrogen gas
    Prashant Choudhary
    Nishel Saini
    Myung Han Yoon
    Kamlendra Awasthi
    Kamakshi Pandey
    Environmental Science and Pollution Research, 2023, 30 : 105387 - 105397
  • [25] ZIF-8 @polycarbonate nanocomposite membranes for improved permeability and selectivity for hydrogen gas
    Choudhary, Prashant
    Saini, Nishel
    Yoon, Myung Han
    Awasthi, Kamlendra
    Pandey, Kamakshi
    ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH, 2023, 30 (48) : 105387 - 105397
  • [26] Development of hybrid models for prediction of gas permeation through FS/POSS/PDMS nanocomposite membranes
    Rezakazemi, Mashallah
    Azarafza, Abouzar
    Dashti, Amir
    Shirazian, Saeed
    INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2018, 43 (36) : 17283 - 17294
  • [27] Effect of solvent type on the morphology and gas permeation properties of polysulfone-silica nanocomposite membranes
    Chenar, Mahdi Pourafshari
    Rajabi, Hamed
    Pakizeh, Majid
    Sadeghi, Morteza
    Bolverdi, Ali
    JOURNAL OF POLYMER RESEARCH, 2013, 20 (08)
  • [28] Gas permeation characteristics and stability of composite silica-metal oxide membranes
    Asaeda, M
    Kanezashi, M
    Yoshioka, T
    Tsuru, T
    MEMBRANES-PREPARATION, PROPERTIES AND APPLICATIONS, 2003, 752 : 213 - 218
  • [29] Effect of film thickness on the gas-permeation characteristics of glassy polymer membranes
    Huang, Y.
    Paul, D. R.
    INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2007, 46 (08) : 2342 - 2347
  • [30] Permeation characteristics of hydrogen through palladium membranes in binary and ternary gas mixtures
    Chen, Wei-Hsin
    Lin, Chien-Nan
    Chi, Yen-Hsun
    Lin, Yu-Li
    INTERNATIONAL JOURNAL OF ENERGY RESEARCH, 2017, 41 (11) : 1579 - 1595