Photoinduced magnetism in CdF2 with bistable donors:: The clue for the negative U?

被引:5
|
作者
Langer, JM [1 ]
Suchocki, A [1 ]
Szymczak, R [1 ]
Baran, M [1 ]
机构
[1] Polish Acad Sci, Inst Phys, PL-02668 Warsaw, Poland
关键词
CdF2 : In; CdF2 : Ga; bistable centres; negative U; photomagnetism;
D O I
10.4028/www.scientific.net/MSF.258-263.1449
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
We report measurements of photoinduced magnetisation of CdF2 bulk crystals doped with In or Ga. At temperatures at which metastable photo transformation of donors occurs, magnetic susceptibility increases and it follows a Curie law. Low magnetic field data are dominated by spin-spin ferromagnetic coupling of d(5) electrons of Mn codopants with donor electrons of In or Ga metastably phototransferred from a localised to the hydrogenic shallow donor state. Enhancement of magnetisation is due to effective spin increase resulting from this coupling. At high magnetic fields (above 2 T) and temperatures below 5K, saturation of the photoinduced magnetisation is observed. This provides first direct proof of a negative-U character of the donors in CdF2.
引用
收藏
页码:1449 / 1454
页数:6
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