Methane gas storage in self-ordered mesoporous carbon (CMK-3)

被引:38
|
作者
Zhou, HS
Zhu, SM
Honma, I
Seki, K
机构
[1] AIST, Energy Elect Inst, Tsukuba, Ibaraki 3058568, Japan
[2] Osaka Gas Co Ltd, Dept Res & Dev, Konohama Ku, Konohama, Osaka 5540051, Japan
关键词
D O I
10.1016/j.cplett.2004.07.120
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We synthesized one kind of hexagonal mesoporous carbon (CMK-3) using hexagonal SBA-15 mesoporous silica as a template. The surface area of the CMK-3 is about 950 m(2)/g, and pore is uniform with a size of 3.90 nm according to the N-2 isotherm curve. The amount of adsorbed methane gas is 81.35 mg/g {= 117.33 ml (STP)/g} at the high pressure 35 kg/cm(2) at room temperature 298 K. The experimental results satisfy an extended Dubinin-Radushkevitch (DR) {1n N = 1n N-L - (DeltaG/betaE(o))2} plot even in the mesopore range. (C) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码:252 / 255
页数:4
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