Transformation of a 1D to 3D coordination polymer mediated by low temperature lattice solvent loss

被引：29
|
作者：
Chesman, Anthony S. R. [1 ]
Turner, David R. [1 ]
Deacon, Glen B. [1 ]
Batten, Stuart R. [1 ]
机构：
[1] Monash Univ, Sch Chem, Clayton, Vic 3800, Australia
来源：
CHEMICAL COMMUNICATIONS | 2010年 / 46卷 / 27期
基金：
澳大利亚研究理事会;
关键词：
MECHANOCHEMICAL PREPARATION; STRUCTURAL TRANSFORMATIONS; METAL-COMPLEXES; NETWORKS; TRINUCLEAR; FRAMEWORK; CRYSTAL; NETS;
D O I：
10.1039/c0cc00711k
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The desolvation of lattice methanol from between the 1D chains in {[Cu(4,4'-bipyridine)(ccnm)(2)]center dot 4MeOH} (ccnm = carbamoylcyanonitrosomethanide) under ambient conditions, a weight loss of 22.4%, results in a solid state conversion to the 3D network [Cu(4,4'-bipyridine)(ccnm)(2)].
引用
收藏
页码：4899 / 4901
页数：3
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