New air-stable iron catalyst for efficient dynamic kinetic resolution of secondary benzylic and aliphatic alcohols

被引：20

作者：

Yang, Qiong ^{[1
]}

Zhang, Na ^{[1
]}

Liu, Mingke ^{[1
]}

Zhou, Shaolin ^{[1
]}

机构：

[1] Cent China Normal Univ, Coll Chem, CCNU uOttawa Joint Res Ctr, Key Lab Pesticide & Chem Biol,Minist Educ, 152 Luoyu Rd, Wuhan 430079, Hubei, Peoples R China

来源：

TETRAHEDRON LETTERS | 2017年 / 58卷 / 25期

关键词：

Dynamic kinetic resolution; Aliphatic alcohol; Benzylic alcohol; Iron catalysis; Racemization; CYCLOPENTADIENONE CATALYST; RACEMIZATION CATALYSTS; ENZYMATIC RESOLUTION; AMBIENT-TEMPERATURE; AROMATIC ALCOHOLS; COMPLEXES; AMINES; HYDROGENATION; RUTHENIUM; LIPASE;

D O I：

10.1016/j.tetlet.2017.05.038

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

We herein report a catalyst system for the dynamic kinetic resolution of secondary alcohols by combining the enzymatic resolution with an iron-catalyzed racemization. A new air-stable tricarbonyl (cyclopentadienone)iron complex is identified as the active racemization catalyst for this transformation without any additive. Various substrates including benzylic, heteroaromatic, aliphatic alcohols can be used and afford the corresponding esters in good yields and with excellent enantioselectivities. (C) 2017 Elsevier Ltd. All rights reserved.

引用

页码：2487 / 2489

页数：3

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