Assembly of two ferrous coordination polymers with triazole derivative: Syntheses, structures and magnetic properties

被引：9
|
作者：
Chen, Yao [1 ]
Zhang, Shi-Yuan [1 ]
Zhao, Xiao-Qing [1 ]
Zhang, Jing-Jing [1 ]
Shi, Wei [1 ,2 ]
Cheng, Peng
机构：
[1] Nankai Univ, Dept Chem, Tianjin 300071, Peoples R China
[2] Nanjing Univ, State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2010年 / 13卷 / 06期
基金：
中国国家自然科学基金;
关键词：
Crystal structure; Fe(II) complex; Coordination polymer; Magnetic property; FRAMEWORKS;
D O I：
10.1016/j.inoche.2010.03.022
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The reactions of Fe(II) salts with 1,4-bis(1,2,4-triazole-1-ylmethyl-benzene) (btx) give two new Fe(II) coordination polymers {[Fe(btx)(3)](ClO4)(2)}(n) (1) and {[Fe(btx)(SO4)(H2O)(2)]}(n) (2), which have been characterized by element analysis, PXRD, single-crystal X-ray diffraction and magnetic susceptibility. 1 shows infinite plait-like chain structure, while 2 exhibits as 2D grid. Magnetic studies indicate that the Fe(II) ions in the two coordination polymers retain in high-spin ground state upon cooling from 300 to 2 K, showing antiferromagnetic interactions. (C) 2010 Elsevier B.V. All rights reserved.
引用
收藏
页码：699 / 702
页数：4
相关论文
共 50 条
  • [21] Syntheses,structures,luminescent and magnetic properties of two coordination polymers based on a flexible multidentate carboxylate ligand
    Dan Tian
    Xiao-Jing Liu
    Rong-Ying Chen
    Ying-Hui Zhang
    Chinese Chemical Letters, 2015, 26 (05) : 499 - 503
  • [22] Hydrothermal syntheses, structures and magnetic properties of two transition metal coordination polymers with a square grid framework
    Zheng, XJ
    Li, LC
    Gao, S
    Jin, LP
    POLYHEDRON, 2004, 23 (07) : 1257 - 1262
  • [23] Syntheses, structures, luminescent and magnetic properties of two coordination polymers based on a flexible multidentate carboxylate ligand
    Tian, Dan
    Liu, Xiao-Jing
    Chen, Rong-Ying
    Zhang, Ying-Hui
    CHINESE CHEMICAL LETTERS, 2015, 26 (05) : 499 - 503
  • [24] Syntheses, structures, and magnetic properties of two gadolinium (III) - Copper(II) coordination polymers by a hydrothermal reaction
    Angewandte Chemie (International Edition in English), 2000, 39 (18): : 3304 - 3307
  • [25] Syntheses, structures, and magnetic properties of two gadolinium(III)-copper(II) coordination polymers by a hydrothermal reaction
    Liang, YC
    Cao, R
    Su, WP
    Hong, MC
    Zhang, WJ
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2000, 39 (18) : 3304 - +
  • [26] Two Lanthanide Coordination Polymers Constructed from Diphenic Acid: Syntheses, Crystal Structures, and Magnetic Properties
    Lv, Dong-Yu
    Gao, Zhu-Qing
    Gu, Jin-Zhong
    Dou, Wei
    SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY, 2010, 40 (02) : 134 - 138
  • [27] Syntheses, structures and magnetic properties of two coordination polymers based on 2,2-biphenyldicarboxylate ligand
    Qingfen Zhang
    Zhongyuan Zhou
    Xuan Wang
    Jing Lu
    Chemical Research in Chinese Universities, 2016, 32 : 165 - 171
  • [28] Syntheses, Structures and Magnetic Properties of Two Coordination Polymers Based on 2,2-Biphenyldicarboxylate Ligand
    Zhang Qingfen
    Zhou Zhongyuan
    Wang Xuan
    Lu Jing
    CHEMICAL RESEARCH IN CHINESE UNIVERSITIES, 2016, 32 (02) : 165 - 171
  • [29] Syntheses,Structures,and Photoluminescent Properties of Two Zn(Ⅱ) Coordination Polymers with Helical Chains Structures
    徐伏
    李付安
    杨维春
    李松田
    结构化学, 2017, 36 (05) : 831 - 840
  • [30] Syntheses, crystal structures, and magnetic properties of 1-D coordination polymers
    Cheng, Qing-Rong
    Li, Ping
    Zhou, Hong
    Pan, Zhi-Quan
    Xu, Zhi-Gao
    Liao, Gui-Ying
    Chen, Jing-Zhong
    JOURNAL OF COORDINATION CHEMISTRY, 2014, 67 (09) : 1584 - 1595
12345