Structural characterization and electrical conductivity studies of BaMoO4 nanofibers prepared by sol-gel and electrospinning techniques

被引:18
|
作者
Jena, Paramananda [1 ]
Nallamuthu, N. [1 ]
Prasad, K. Hari [1 ]
Venkateswarlu, M. [2 ]
Satyanarayana, N. [1 ]
机构
[1] Pondicherry Univ, Dept Phys, Pondicherry 605014, India
[2] R&D Amara Raja Batteries Ltd, Karakambadi 517501, AP, India
关键词
Sol-gel process; Electrospinning technique; Scheelite type; Nanofibers; Electrical conductivity; SPINEL LIMN2O4; CITRATE ROUTE; CA; SR; BA; FABRICATION; TUNGSTATES; TRANSPORT; CERAMICS; SPECTRA;
D O I
10.1007/s10971-014-3460-z
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Scheelite type BaMoO4 nanofibers were prepared by using acrylamide assisted sol-gel process and electrospinning technique. The prepared Scheelite BaMoO4 nanofibers were characterized by using TG/DTA, XRD, FTIR, FT-Raman and SEM-EDX techniques. Thermal behavior, crystalline phase and structure of the prepared BaMoO4 nanofibers samples were confirmed from the analysis of the obtained results of TG/DTA, XRD, FTIR and FT-Raman respectively. SEM micrographs along with EDX showed the formation of one dimensional (1D) nanofibers 100-350 nm diameters and existence of Ba, Mo and O elements in the BaMoO4 nanofibers sample. The electrical conductivity of BaMoO4 nanofibers as a function of temperature 200-400 A degrees C under air was evaluated by analyzing the measured impedance data using the winfit software. The newly prepared Scheelite type BaMoO4 nanofibers showed electrical conductivity of 0.92 x 10(-3) S/cm at 400 degrees C.
引用
收藏
页码:480 / 489
页数:10
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