Two novel dyes containing spirobifluorene and triphenylamine: Synthesis, one- and two-photon excited fluorescence and applications as probes for silver ions, water and cell imaging

被引：32
|
作者：
Xiao, Haibo [1 ]
Zhang, Yanzhen [1 ]
Zhang, Wu [1 ]
Li, Shaozhi [1 ]
Xu, Ronghua [1 ]
机构：
[1] Shanghai Normal Univ, Dept Chem, Shanghai 200234, Peoples R China
来源：
SENSORS AND ACTUATORS B-CHEMICAL | 2016年 / 233卷
基金：
上海市自然科学基金;
关键词：
Two-photon excited fluorescence; Probe; Silver ion; Cell imaging; Water content; STABILITY TRADE-OFF; ORGANIC-SOLVENTS; MERCURY ION; SENSOR; CHEMOSENSOR; ABSORPTION; COMPLEX; SERIES;
D O I：
10.1016/j.snb.2016.04.101
中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
Two fluorophores, SPF-TNS and SPF-TBB, with electron-rich triphenylamine groups and Ag+ receptor units on the respective biphenyl branches of 9,9'-spirobifluorene were synthesized. They exhibit strong one- and two-photon excited fluorescence, and the two-photon absorption cross-section values are 665 GM for SPF-TNS and 355GM for SPF-TBB. The probing behaviors toward metal ions were investigated via UVIVis absorption spectra as well as one-photon fluorescence changes. The results indicated that SPF-TNS and SPF-TBB exhibit distinct fluorescent quenching in the presence of silver ions that can be used for highly sensitive and selective naked-eye detection of Ag+ The one-photon excited fluorescence of SPF-TBB can be made to measure water content of organic solvents. The detection limits were calculated to be 0.04% for THE and 0.03% for 1,4-dioxane. The two-photon scanning microscopy experiments suggest that SPF-TNS is a promising label potentially applicable for the tracking of biomolecules. (C) 2016 Elsevier B.V. All rights reserved.
引用
收藏
页码：469 / 475
页数：7
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