Optical spectroscopy of Re3+ ions in sol-gel prepared α-Al2O3

被引:1
|
作者
Feofilov, SP [1 ]
Kaplyanskii, AA [1 ]
Kulinkin, AB [1 ]
Kutsenko, AB [1 ]
Vasilevskaya, TN [1 ]
Zakharchenya, RI [1 ]
机构
[1] AF Ioffe Phys Tech Inst, St Petersburg 194021, Russia
来源
RADIATION EFFECTS AND DEFECTS IN SOLIDS | 1999年 / 151卷 / 1-4期
关键词
nanocrystals; sol-gel technology; rare-earth ions; fluorescence spectra;
D O I
10.1080/10420159908245947
中图分类号
TL [原子能技术]; O571 [原子核物理学];
学科分类号
0827 ; 082701 ;
摘要
The monolithic polycrystalline small-grain corundum alpha-Al2O3 doped with trivalent rare earth ions RE3+ (Eu3+, Er3+, Pr3+) was produced for the first time using the sol-gel technology. The fluorescence and absorption spectra of these materials were studied which exhibit the sets of narrow lines belonging to f-f transitions between RE3+ states. It was shown that Eu3+ and Er3+ ions form in corundum lattice the single dominating type of regular centers. The energy scheme of Stark sublevels for ground and excited states of dominating Eu3+ and Er3+ centers in corundum was determined.
引用
收藏
页码:131 / 135
页数:5
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