Synthesis, spectroscopic characterisation and structure of the first chiral heteroleptic bis(phthalocyaninato) rare earth complexes

被引：65
|
作者：
Bian, YZ
Wang, RM
Jiang, JZ [1 ]
Lee, CH
Wang, JZ
Ng, DKP
机构：
[1] Shandong Univ, Dept Chem, Jinan 250100, Peoples R China
[2] Chinese Univ Hong Kong, Dept Chem, Shatin, Hong Kong, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2003年 / 10期
关键词：
D O I：
10.1039/b301139a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Treatment of M-III(Pc)(acac) (M = Sm, Eu, Gd; Pc = phthalocyaninate; acac = acetylacetonate), generated in situ, with 3-( 3- pentyloxy) phthalonitrile in the presence of 1,8-diazabicyclo[5.4.0] undec-7-ene(DBU) in n-pentanol affords racemic mixtures of the chiral double-deckers M-III(Pc)[Pc(OC5H11)(4)] [Pc(OC5H11)(4) = 1,8,15,22-tetrakis( 3-pentyloxy) phthalocyaninate], which have been spectroscopically and structurally characterised.
引用
收藏
页码：1194 / 1195
页数：2
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