Palladium-catalyzed synthesis of aqueous, fluorous, and supercritical CO2-soluble phosphines

被引：54
|
作者：
Chen, WP [1 ]
Xu, LJ [1 ]
Xiao, JL [1 ]
机构：
[1] Univ Liverpool, Dept Chem, Leverhulme Ctr Innovat Catalysis, Liverpool L69 7ZD, Merseyside, England
来源：
ORGANIC LETTERS | 2000年 / 2卷 / 17期
关键词：
D O I：
10.1021/ol006203+
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
[GRAPHICS] A generic, simple, and economical route has been developed for the synthesis of phosphines soluble in aqueous, fluorous, and supercritical CO2 phases. The methodology is based on the palladium-catalyzed Heck olefination of haloary/phosphine oxides followed by reduction, affording various arylphosphines in high yields.
引用
收藏
页码：2675 / 2677
页数：3
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