Fabrication of tubular NiO/YSZ anode-support of solid oxide fuel cell by gelcasting

被引:48
|
作者
Dong, Dehua [1 ]
Gao, Jianfeng [1 ]
Liu, Xingqin [1 ]
Meng, Guangyao [1 ]
机构
[1] Univ Sci & Technol China, Dept Mat Sci & Engn, Hefei 230026, Peoples R China
基金
中国国家自然科学基金;
关键词
gelcasting; solid oxide fuel cells; tubular anode-support; microstructure;
D O I
10.1016/j.jpowsour.2006.10.098
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A gelcasting process has been developed to fabricate tubular NiO/YSZ anode-support for solid oxide fuel cells (SOFCs) successfully. The theological behaviors of the ceramic particle suspensions for gelcasting were investigated as a function of the process parameters, such as the amount of pore former, pH value, dispersant concentration, monomer concentration, ball-mill time and solid loading. The sintering shrinkage, microstructure, bending strength and electrical conductivity of the sintered specimens were examined. The tubular Ni/YSZ anode-support obtained under the optimized preparation conditions exhibited a porosity of 39.6%, mean pore size of below 0.9 mu m, 482 s cm(-1) in electrical conductivity at 700 degrees C, and the bending strength of 112.8 MPa, which can well meet the requirements for SOFCs. (c) 2006 Elsevier B.V. All rights reserved.
引用
收藏
页码:217 / 223
页数:7
相关论文
共 50 条
  • [31] Reduction kinetics of NiO–YSZ composite for application in solid oxide fuel cell
    W. K. Yoshito
    J. R. Matos
    V. Ussui
    D. R. R. Lazar
    J. O. A. Paschoal
    Journal of Thermal Analysis and Calorimetry, 2009, 97 : 303 - 308
  • [32] Carbothermal reduction of the YSZ-NiO solid oxide fuel cell anode precursor by carbon-based materials
    Arico, E.
    Tabuti, F.
    Fonseca, F. C.
    de Florio, D. Z.
    Ferlauto, A. S.
    JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2009, 97 (01) : 157 - 161
  • [33] Fabrication and properties of anode-supported tubular solid oxide fuel cells
    Du, YH
    Sammes, NM
    JOURNAL OF POWER SOURCES, 2004, 136 (01) : 66 - 71
  • [34] Fabrication and Performance of Anode-Supported Flat Tubular Solid Oxide Fuel Cell Unit Bundle
    Lim, Tak-Hyoung
    Kim, Gwan-Yeong
    Park, Jae-Layng
    Lee, Seung-Bok
    Shin, Dong-Ryul
    Song, Rak-Hyun
    JOURNAL OF THE KOREAN ELECTROCHEMICAL SOCIETY, 2007, 10 (04): : 283 - 287
  • [35] Fabrication of anode supported PEN for solid oxide fuel cell
    谢淑红
    崔崑
    夏风
    肖建中
    电池, 2004, (03) : 209 - 211
  • [36] Recent fabrication techniques for micro-tubular solid oxide fuel cell support: A review
    Jamil, Siti Munira
    Othman, Mohd Hafiz Dzarfan
    Rahman, Mukhlis A.
    Jaafar, Juhana
    Ismail, A. F.
    Li, K.
    JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 2015, 35 (01) : 1 - 22
  • [37] Porosity, microstructure and mechanical behavior of NiO-YSZ composite anode for solid oxide fuel cells
    Tanhaei, Mohammad
    Mozammel, Mandi
    Javanshir, Ehsan
    Lkhechi, Nasrollah Najibi
    INTERNATIONAL JOURNAL OF MATERIALS RESEARCH, 2017, 108 (10) : 857 - 863
  • [38] Fabrication of anode support for solid oxide fuel cell using zirconium hydroxide as a pore former
    Kim, Minchul
    Lee, Jaehyung
    Han, Joo-Hwan
    JOURNAL OF POWER SOURCES, 2011, 196 (05) : 2475 - 2482
  • [39] Influence of processing conditions on the microstructure of NiO-YSZ supporting anode for solid oxide fuel cells
    Casarin, Michele
    Sglavo, Vincenzo M.
    CERAMICS INTERNATIONAL, 2015, 41 (02) : 2543 - 2557
  • [40] Solid oxide fuel cell with oxide anode-side support
    Pillai, Manoj R.
    Jiang, Yi
    Mansourian, Negar
    Kim, Ilwon
    Bierschenk, David M.
    Zhu, Huayang
    Kee, Robert J.
    Barnett, Scott A.
    ELECTROCHEMICAL AND SOLID STATE LETTERS, 2008, 11 (10) : B174 - B177