In situ IR studies on the mechanism of methanol synthesis from CO/H2 and CO2/H2 over Cu-ZnO-Al2O3 catalyst

被引：22

作者：

Wang, Xiaojuan ^{[1
]}

Zhang, Haipeng ^{[1
]}

Li, Wei ^{[1
]}

机构：

[1] E China Univ Sci & Technol, State Key Lab Chem Engn, Shanghai 200237, Peoples R China

来源：

KOREAN JOURNAL OF CHEMICAL ENGINEERING | 2010年 / 27卷 / 04期

关键词：

Methanol Synthesis; Mechanism; In Situ; FT-IR; CO HYDROGENATION; CARBON-MONOXIDE; FT-IR; PRESSURE; DIOXIDE; CU/ZNO; ZNO;

D O I：

10.1007/s11814-010-0176-9

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Methanol synthesis from CO/H-2 and CO2/H-2 was carried out at atmospheric pressure over Cu/ZnO/Al2O3 catalyst. The formation and variation of surface species were recorded by in situ FT-IR spectroscopy. The result revealed that both CO and CO2 can serve as the primary carbon source for methanol synthesis. For CO/H-2 feed gas, only HCOO-Zn was detected; however, for CO2/H-2, both HCOO-Zn and HCOO-Cu were observed, and without CH3O-Cu. HCOO-Zn was the key intermediate. A scheme of methanol synthesis and reverse water-gas shift (RGWS) reaction was proposed.

引用

页码：1093 / 1098

页数：6

共 50 条

[31] The Partial Oxidation of CH3OH to CO2 and H2 Over a Cu/ZnO/Al2O3 Catalyst
S. Ellis
B.H. Sakakini
R. Torbati
K.C. Waugh
Catalysis Letters, 2002, 82 : 261 - 270
[32] DME Synthesis From CO/H2 over Cu-Mn/Ă-Al2O3 Catalyst
Gong-Xin Qi
Jin-Hua Fei
Xiao-Ming Zheng
Zhao-Yin Hou
Reaction Kinetics and Catalysis Letters, 2001, 73 : 245 - 256
[33] DME synthesis from CO/H2 over Cu-Mn/γ-Al2O3 catalyst
Qi, GX
Fei, JH
Zheng, XM
Hou, ZY
REACTION KINETICS AND CATALYSIS LETTERS, 2001, 73 (02): : 245 - 256
[34] A Novel Process for the Preparation of Cu/ZnO and Cu/ZnO/Al2O3 Ultrafine Catalyst: Structure, Surface Properties, and Activity for Methanol Synthesis from CO2 + H2
J Catal, 1 (92):
[35] The Influence of the Precipitation/Ageing Temperature on a Cu/ZnO/ZrO2 Catalyst for Methanol Synthesis from H2 and CO2
Frei, Elias
Schaadt, Achim
Ludwig, Thilo
Hillebrecht, Harald
Krossing, Ingo
CHEMCATCHEM, 2014, 6 (06) : 1721 - 1730
[36] Influence of titania on zirconia promoted Cu/SiO2 catalysts for methanol synthesis from CO/H2 and CO2/H2
Tobin C. Schilke
Ian A. Fisher
Alexis T. Bell
Catalysis Letters, 1998, 54 : 105 - 111
[37] Influence of titania on zirconia promoted Cu/SiO2 catalysts for methanol synthesis from CO/H2 and CO2/H2
Schilke, TC
Fisher, IA
Bell, AT
CATALYSIS LETTERS, 1998, 54 (03) : 105 - 111
[38] In Situ Generation of the Cu@3D-ZrOx Framework Catalyst for Selective Methanol Synthesis from CO2/H2
Liu, Tangkang
Hong, Xinlin
Liu, Guoliang
ACS CATALYSIS, 2020, 10 (01) : 93 - 102
[39] Vapor phase methylation of pyridine with CO−H2 and CO2−H2 over a Ni catalyst
Shin-ichiro Fujita
Norihito Hiyoshi
Nobutsune Takezawa
Reaction Kinetics and Catalysis Letters, 1999, 67 : 9 - 12
[40] Kinetics of CO and H2 oxidation over CuO-CeO2 catalyst in H2 mixtures with CO2 and H2O
Lee, Hyun Chan
Kim, Dong Hyun
CATALYSIS TODAY, 2008, 132 (1-4) : 109 - 116

← 1 2 3 4 5 →