The temperature dependence of C-H•••F-C interactions in benzene : hexafluorobenzene

被引：32
|
作者：
Cockcroft, Jeremy K. [1 ]
Rosu-Finsen, Alexander [1 ]
Fitch, Andrew N. [2 ]
Williams, Jeffrey H.
机构：
[1] UCL, Christopher Ingold Labs, Dept Chem, 20 Gordon St, London WC1H 0AJ, England
[2] European Synchrotron Radiat Facil, 71 Ave Martyrs,CS 40220, F-38043 Grenoble 9, France
来源：
CRYSTENGCOMM | 2018年 / 20卷 / 42期
基金：
英国工程与自然科学研究理事会;
关键词：
CRYSTAL-STRUCTURE; SOLID BENZENE; PHASE; COMPLEX; MESITYLENE; FLUORINE; DYNAMICS;
D O I：
10.1039/c8ce01187g
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The evolution of the structure of the four solid phases of the prototype binary-adduct C6H6:C6F6 as a function of temperature has been investigated using X-ray and neutron diffraction. An explanation is proposed concerning changes in the arrangements of the molecules at each of the three phase transitions and the dynamics in C6H6:C6F6 are briefly compared with those of the adduct formed between mesitylene and C6F6. The observations are rationalised using simple models of intermolecular electrostatics.
引用
收藏
页码：6677 / 6682
页数：6
相关论文
共 50 条
  • [31] F-C柜综述
    何利利
    高压电器, 1995, (01) : 42 - 48+52
  • [32] A mixed crystal of imperatorin and phellopterin, with C-H•••O, C-H•••π and π-π interactions
    Cox, PJ
    Jaspars, M
    Kumarasamy, Y
    Nahar, L
    Sarker, SD
    Shoeb, M
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 2003, 59 (09) : O520 - O522
  • [33] Selinidin:: Crystal structure generated by C-H•••O, C-H•••π and π-π interactions
    Goswami, Sanjeev
    Gupta, Vivek K.
    Raina, S.
    Gupta, B. D.
    JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 2006, 36 (02) : 117 - 122
  • [34] THE C-H BOND-ENERGY OF BENZENE
    DAVICO, GE
    BIERBAUM, VM
    DEPUY, CH
    ELLISON, GB
    SQUIRES, RR
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (09) : 2590 - 2599
  • [35] Modeling of High-Temperature Ordered Structures with Weak Intermolecular C-H•••F and C-H•••N Bonds
    Ibenskas, Andrius
    Tornau, Evaldas E.
    JOURNAL OF PHYSICAL CHEMISTRY C, 2021, 125 (35): : 19560 - 19569
  • [36] Bifurcated CH2•••O and (C-H)2•••F-C weak hydrogen bonds:: The oxirane-difluoromethane complex
    Blanco, S
    López, JC
    Lesarri, A
    Caminati, W
    Alonso, JL
    CHEMPHYSCHEM, 2004, 5 (11) : 1779 - 1782
  • [37] Energetically Important C-H•••F-C Pseudohydrogen Bonding in Water: Evidence and Application to Rational Design of Oligonucleotides with High Binding Affinity
    Anzahaee, Maryam Yahyaee
    Watts, Jonathan K.
    Alla, Nageswara R.
    Nicholson, Allen W.
    Damha, Masad J.
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (04) : 728 - 731
  • [38] Two isomorphous benzenesulfonamide crystal structures determined by intermolecular C-H•••O,C-H•••π and C-H•••Cl interactions
    Bats, JW
    Frost, TM
    Hashmi, ASK
    ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2001, 57 (09): : 1081 - 1083
  • [39] Directionality of intermolecular C-F•••F-C interactions in crystals: experimental and theoretical charge density study
    Karnoukhova, V. A.
    Fedyanin, I. V.
    Lyssenko, K. A.
    STRUCTURAL CHEMISTRY, 2016, 27 (01) : 17 - 24
  • [40] Benzene 1,3,5-tris(p-toluenesulfonate):: supramolecular aggregation through extensive C-H•••O, C-H•••π and π-π interactions
    Vembu, N
    Nallu, M
    Garrison, J
    Youngs, WJ
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2003, 59 : O1019 - O1021
12345