C-S bond formation catalyzed by N-heterocylic carbene palladium phosphine complexes

被引：41

作者：

Fu, Ching-Feng ^{[1
]}

Liu, Yi-Hung ^{[1
]}

Peng, Shei-Ming ^{[1
]}

Liu, Shiuh-Tzung ^{[1
]}

机构：

[1] Natl Taiwan Univ, Dept Chem, Taipei 106, Taiwan

来源：

TETRAHEDRON | 2010年 / 66卷 / 12期

关键词：

Palladium; N-Heterocyclic carbene; C-S coupling; Sulfide; CROSS-COUPLING REACTIONS; ARYL HALIDES; THIOLS; CHEMISTRY; REACTIVITY; CHLORIDES; SYSTEM;

D O I：

10.1016/j.tet.2010.01.081

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

N-Heterocyclic carbenes (NHCs) are known to be useful ligands for palladium-complex catalysis It was found that [(NHC)Pd(PPh3)Cl-2] is an effective pre-catalyst in Pd-catalyzed C-S cross coupling reactions to produce the functionalized sulfides in excellent yields The turn over frequency (TOF) for the coupling of p-CH3C6H4Bi with p-CH3C6H4SH reaches to 6 25 (mol Of product) (mole of catalyst)(-1) h(-1) (C) 2010 Elsevier Ltd All rights reserved

引用

页码：2119 / 2122

页数：4

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