Synthesis and Characterization of 2,3-Diaminomaleonitrile Derivatives by One-Pot Schiff Base Reaction and Their Application in Dye Synthesized Solar Cells

被引：5

作者：

Abdalhadi, Saifaldeen Muwafag ^{[1
]}

Al-Baitai, Asmaa Yahya ^{[2
]}

Al-Zubaidi, Hazim Abdulrazzaq ^{[3
]}

机构：

[1] Al Karkh Univ Sci, Coll Remote Sensing & Geophys, Dept Remote Sensing, Baghdad, Iraq

[2] Al Nahrain Univ, Coll Sci, Dept Chem, Baghdad, Iraq

[3] Al Karkh Univ Sci, Coll Sci, Dept Biomed Sci, Baghdad, Iraq

来源：

INDONESIAN JOURNAL OF CHEMISTRY | 2021年 / 21卷 / 02期

关键词：

one-pot reaction; 2,3-diaminomaleonitrile; Schiff base; DSSCs; ORGANIC SENSITIZERS; RAPID SYNTHESIS; COUMARIN DYE; EFFICIENT; DSSC; DESIGN; ENERGY; PROGRESS; FURAN;

D O I：

10.22146/ijc.57535

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In a one-pot reaction, three new 2,3-diaminomaleonitrile (DAMN) derivative dyes were prepared by simple Schiff base reaction. The compounds were designed as a sensitizer in dye synthesizes solar cells (DSSCs). Many conditions have been used to provide the methodology to get the best yield. The prepared dyes were characterized by melting point, elemental microanalysis, mass spectroscopy, FT-IR, H-1-NMR, and UV-Vis spectroscopy. A computational study was carried out to support our results. The DSSC data was shown the best performance for SA3 dye with 0.38% efficiency at AM 1.5 then SA2 with 0.22% and the last dye is SA1 with 0.09%, compared to control cell (N719) 5.4%.

引用

页码：443 / 451

页数：9

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