Diversity-Oriented Synthesis of Calothrixins and Ellipticines

被引:21
|
作者
Dethe, Dattatraya H. [1 ]
Murhade, Ganesh M. [1 ]
机构
[1] Indian Inst Technol, Dept Chem, Kanpur 208016, Uttar Pradesh, India
关键词
Natural products; Nitrogen heterocycles; Quinones; Rearrangement; Oxidation; FACILE SYNTHESIS; LEAD-TETRAACETATE; ROUTE; DERIVATIVES; ALKALOIDS; ANALOGS; ENTRY;
D O I
10.1002/ejoc.201402837
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The divergent synthesis of calothrixins and ellipticines has been accomplished by utilising the one-pot formation of o-diacylarenes as a key intermediate through rearrangement of o-hydroxy ketone monoacyl hydrazones by lead tetraacetate mediated oxidation.
引用
收藏
页码:6953 / 6962
页数:10
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