Oxidation of 5-hydroxymethylfurfural to 2,5-diformylfuran with molecular oxygen in the presence of N-hydroxyphthalimide

被引：27

作者：

Kornpanets, M. O. ^{[1
]}

Kushch, O. V. ^{[1
]}

Litvinov, Yu E. ^{[1
]}

Pliekhov, O. L. ^{[1
]}

Novikova, K. V. ^{[1
]}

Novokhatko, A. O. ^{[1
]}

Shendrik, A. N. ^{[2
]}

Vasilyev, A. V. ^{[3
,4
]}

Opeida, I. O. ^{[1
]}

机构：

[1] NASU, LM Litvinenko Inst Phys Organ & Coal Chem, UA-83114 Donetsk, Ukraine

[2] Donetsk Natl Univ, UA-83055 Donetsk, Ukraine

[3] St Petersburg State Forest Tech Univ, Dept Organ Chem, St Petersburg 194021, Russia

[4] St Petersburg State Univ, Fac Chem, Dept Organ Chem, St Petersburg 198504, Russia

来源：

CATALYSIS COMMUNICATIONS | 2014年 / 57卷

基金：

俄罗斯科学基金会;

关键词：

Aerobic oxidation; N-hydroxyphthalimide; Homogenous catalysis; 5-Hydroxymethylfurfural; Kinetics; 2,5-Diformylfuran; AEROBIC OXIDATION; MILD CONDITIONS; ALCOHOLS; MECHANISM; ALDEHYDES; POLAR;

D O I：

10.1016/j.catcom.2014.08.005

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Catalytic system Cu(NO3)(2)/NHPI can be successfully used for the mild oxidation of 5-hydroxymethylfurfural (HMF) to 2,5-diformylfuran with molecular oxygen. The oxidation reaction takes place at 50 degrees C and 1 atm O-2 and selectively converts the primary hydroxymethyl group of HMF to the aldehyde one. The selective formation of aromatic aldehyde is observed because of the higher rate of hydrogen abstraction from primary alcohols by the phthalimide-N-oxyl radical, as compared to the rate of the hydrogen abstraction from the aldehydes. (C) 2014 Elsevier B.V. All rights reserved.

引用

页码：60 / 63

页数：4

共 50 条

[31] Conversion of 5-Hydroxymethylfurfural and Carbohydrates to 2,5-Diformylfuran Over MoOx/Biochar Catalysts
Yang, Delong
Du, Ziting
Dai, Jinhang
Cao, Qingya
Xiang, Zhaobao
Chen, Gang
Li, Fukun
ChemNanoMat, 2024, 10 (10)
[32] Catalytic oxidation of 5-hydroxymethylfurfural into 2,5-diformylfuran using V-containing heteropoly acid catalysts
Rodikova, Yulia
Zhizhina, Elena
REACTION KINETICS MECHANISMS AND CATALYSIS, 2020, 130 (01) : 403 - 415
[33] Selective Catalytic Oxidation of 5-Hydroxymethylfurfural to Produce 2,5-Diformylfuran Over Nitrogen Doped Porous Carbons
Zhou, Shuolin
Wen, Sha
Xu, Qiong
Liu, Xianxiang
Yin, Dulin
CATALYSIS LETTERS, 2024, 154 (07) : 3494 - 3502
[34] Selective oxidation of 5-hydroxymethylfurfural to 2,5-diformylfuran over niobium incorporated MCM-41 catalyst
Mahendran, S.
Srinivasan, V. V.
Karthikeyan, G.
Pachamuthu, M. P.
MOLECULAR CATALYSIS, 2021, 510
[35] Mesoporous manganese doped cobalt oxide catalysts for selective aerobic oxidation of 5-hydroxymethylfurfural to 2,5-diformylfuran
Biswas, Sourav
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2018, 256
[36] Efficient oxidation of biomass derived 5-hydroxymethylfurfural into 2,5-diformylfuran catalyzed by NiMn layered double hydroxide
Zhou, Weiyou
Kong, Zhenji
Wu, Zhong
Yang, Song
Wang, Yu
Liu, Yupeng
CATALYSIS COMMUNICATIONS, 2021, 151 (151)
[37] Catalytic oxidation of 5-hydroxymethylfurfural into 2,5-diformylfuran using V-containing heteropoly acid catalysts
Yulia Rodikova
Elena Zhizhina
Reaction Kinetics, Mechanisms and Catalysis, 2020, 130 : 403 - 415
[38] Copper-Catalyzed Oxidation of 5-Hydroxymethylfurfural to 2,5-Diformylfuran Assisted by TEMPOL in Liquid Sunlight Methanol
Li, Xing-Long
Qing, Shao-Jun
Sun, Xun
Yu, Zhen
Xu, Hua-Jian
Fu, Yao
CHEMSUSCHEM, 2025, 18 (02)
[39] V2O5/SBA-15 Nanocatalysts for the Selective Oxidation of 5-Hydroxymethylfurfural into 2,5-Diformylfuran
Liao, Longfei
Liu, Ying
Wu, Shubin
JOURNAL OF BIOBASED MATERIALS AND BIOENERGY, 2018, 12 (04) : 321 - 329
[40] Cu catalyzed oxidation of 5-hydroxymethylfurfural to 2,5-diformylfuran and 2,5-furandicarboxylic acid under benign reaction conditions
Hansen, Thomas S.
Sadaba, Irantzu
Garcia-Suarez, Eduardo J.
Riisager, Anders
APPLIED CATALYSIS A-GENERAL, 2013, 456 : 44 - 50

← 1 2 3 4 5 →