Synthesis and crystal structure of [Ni(C5H5N)2(C7H6O2N)2]•H2O

被引：0

作者：

Jiang, YM ^{[1
]}

Zhang, SH

Xiao, Y

Zhong, XX

Zhou, ZY

机构：

[1] Guangxi Normal Univ, Dept Chem, Guilin 541004, Peoples R China

[2] Guilin Inst Technol, Guilin 541004, Peoples R China

[3] Hong Kong Polytech Univ, Dept Appl Biol & Chem Technol, Hong Kong, Hong Kong, Peoples R China

来源：

CHINESE JOURNAL OF STRUCTURAL CHEMISTRY | 2003年 / 22卷 / 03期

关键词：

nickel complex; salicylicimine pyridine; crystal structure;

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The complex [Ni(C5H5N)(2)(C7H6O2N)(2)].H2O was synthesized by the reaction of taurine salicylic Schiff base(TSSB), pyridine and nickel acetate in water-ethanol solution, and determined by X-ray diffraction method; but it was showed that the compound does not contain taurine. It belongs to monoclinic system, space group C2/c with a = 14.466(2), b = 12.193(2), c = 14.072(2) Angstrom,beta = 116.229(2)degrees, M-r = 475.18, V = 2226.6(5) Angstrom(3), Z = 4, D-c = 1.418 g/cm(3), mu = 0.905 mm(-1) and F(000) = 992. The complex is two-dimensional formed through hydrogen bonding. The Ni(II), coordinated by two oxygen atoms from two salicylic imine molecules and four nitrogen atoms from two pyridines and two salicylic imine molecules, forms an octahedral geometry. The abilities of various atoms coordinating to Ni(II) are also discussed

引用

页码：355 / 358

页数：4