catena-Poly[[(nitrato-κ2O,O′)-silver(I)]-μ-2,2′-[1,4-phenylenebis(methylenethio)]bis(5-methyl-1,3,4-thiadiazole)-κ2N3:N3′]

被引：4
|
作者：
Zheng, Y [1 ]
机构：
[1] Tianjin Univ, Dept Chem, Tianjin 300072, Peoples R China
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 2004年 / 60卷
关键词：
D O I：
10.1107/S0108270104019183
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
In the title complex, [Ag(NO3)(C14H14N4S4)](n), the Ag-I atom lies on a twofold axis and shows a distorted tetrahedral coordination, comprised of two N-atom donors from two thiadiazole groups of separate ligands and two O-atom donors from one nitrate ligand. Each bis(thioether) ligand also lies on a twofold axis and bridges two adjacent Ag atoms to form an infinite chain along the c axis, with an Ag...Ag separation of 11.462 (4) Angstrom. Adjacent one-dimensional chains are further linked into double-chain motifs through weak Ag...S and pi-pi stacking interactions.
引用
收藏
页码：M471 / M472
页数：2
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