Metal-Organic Cooperative Catalysis in C-H and C-C Bond Activation

被引：542
|
作者：
Kim, Dong-Su [1 ]
Park, Woo-Jin [1 ]
Jun, Chul-Ho [1 ]
机构：
[1] Yonsei Univ, Dept Chem, 50 Yonsei Ro, Seoul 03722, South Korea
来源：
CHEMICAL REVIEWS | 2017年 / 117卷 / 13期
基金：
新加坡国家研究基金会;
关键词：
CHELATION-ASSISTED HYDROACYLATION; SUBSTITUTED ARYL IODIDES; TETRASUBSTITUTED HELICAL ALKENES; TOSYLHYDRAZONE INSERTION REACTION; ALKYLATION-ALKENYLATION REACTIONS; CONCOMITANT ORTHO-ALKYLATION; CATELLANI ORTHO-ARYLATION; CARBON-CARBON BONDS; ONE-POT SYNTHESIS; INTERMOLECULAR HYDROACYLATION;
D O I：
10.1021/acs.chemrev.6b00554
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Transition-metal-catalyzed activation of C-H and C-C bonds is a challenging area in synthetic organic chemistry. Among various methods to accomplish these processes, the approach using metal organic cooperative catalytic systems is one of the most promising. In this protocol, organic molecules as well as transition metals act as catalysts to bring about reactions, which proceed with high efficiencies and selectivities. Various metal organic cooperative catalytic systems developed for C-H and C-C bond activation reactions are discussed in this review. Also discussed are how each metal organic cooperative catalyst affects the reaction mechanism and what kinds of substrates can be applied in each of the catalytic processes.
引用
收藏
页码：8977 / 9015
页数：39
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