Epitaxy driven interactions at the organic-inorganic interface during biomimetic growth of calcium oxalate

被引：7
|
作者：
Uysal, Ahmet [1 ]
Stripe, Benjamin [1 ]
Kim, Kyungil [2 ]
Dutta, Pulak [1 ]
机构：
[1] Northwestern Univ, Dept Phys & Astron, Evanston, IL 60208 USA
[2] Univ Chicago, CARS, Chicago, IL 60637 USA
来源：
CRYSTENGCOMM | 2010年 / 12卷 / 07期
基金：
美国国家科学基金会;
关键词：
LANGMUIR MONOLAYERS; PHOSPHOLIPID MONOLAYERS; MOLECULAR OVERLAYERS; AMINO-ACIDS; IN-VITRO; MONOHYDRATE; CRYSTALLIZATION; CRYSTALS; NUCLEATION; TEMPLATE;
D O I：
10.1039/b926751d
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
During oriented biomimetic crystallization of calcium oxalate monohydrate under floating fatty acid monolayers, the ((1) over bar 01) surface structure is initially compressed and epitaxial with the monolayer lattice. The surface subsequently relaxes to the bulk structure and the monolayer expands, reestablishing a lattice match. These interactions were observed in situ using synchrotron X-ray diffraction.
引用
收藏
页码：2025 / 2028
页数：4
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