Clicking not cooking: Functionalization of 2,2′:6′,2"-terpyridines by diol-boric acid interactions

被引：4

作者：

Constable, Edwin C. ^{[1
]}

Zhang, Guoqi ^{[1
]}

Housecroft, Catherine E. ^{[1
]}

Neuburger, Markus ^{[1
]}

机构：

[1] Univ Basel, Dept Chem, CH-4056 Basel, Switzerland

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2010年 / 13卷 / 07期

基金：

瑞士国家科学基金会;

关键词：

2,2':6',2 ''-Terpyridine; Boronic acid; Modular strategy; Structure; CHEMISTRY; COMPLEXES; CATECHOL; MACROMOLECULES; BINUCLEAR; RUTHENIUM; SERIES; LIGAND;

D O I：

10.1016/j.inoche.2010.04.019

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A diol-boric acid condensation is a simple type of CLICK reaction that can be applied to give a family of related ligands. It is exemplified by the reaction of 4'-(3,4-dihydroxyphenyl)-2,2':6',2 ''-terpyridine (1) with naphthalene-1-boronic acid. The single crystal structures of 1 center dot MeOH and [Fe(1)(2)][BF(4)](2)center dot 4H(2)O center dot 0.2CH(3)CN are presented. (C) 2010 Elsevier B.V. All rights reserved.

引用

页码：878 / 881

页数：4

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