Clicking not cooking: Functionalization of 2,2′:6′,2"-terpyridines by diol-boric acid interactions

被引：4
|
作者：
Constable, Edwin C. [1 ]
Zhang, Guoqi [1 ]
Housecroft, Catherine E. [1 ]
Neuburger, Markus [1 ]
机构：
[1] Univ Basel, Dept Chem, CH-4056 Basel, Switzerland
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2010年 / 13卷 / 07期
基金：
瑞士国家科学基金会;
关键词：
2,2':6',2 ''-Terpyridine; Boronic acid; Modular strategy; Structure; CHEMISTRY; COMPLEXES; CATECHOL; MACROMOLECULES; BINUCLEAR; RUTHENIUM; SERIES; LIGAND;
D O I：
10.1016/j.inoche.2010.04.019
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A diol-boric acid condensation is a simple type of CLICK reaction that can be applied to give a family of related ligands. It is exemplified by the reaction of 4'-(3,4-dihydroxyphenyl)-2,2':6',2 ''-terpyridine (1) with naphthalene-1-boronic acid. The single crystal structures of 1 center dot MeOH and [Fe(1)(2)][BF(4)](2)center dot 4H(2)O center dot 0.2CH(3)CN are presented. (C) 2010 Elsevier B.V. All rights reserved.
引用
收藏
页码：878 / 881
页数：4
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