Radiation-induced oxidation of thiaproline derivatives in frozen acidic aqueous solutions: theoretical and electron spin resonance study

被引：0
|
作者：
Pogocki, D
Sadlo, J
机构：
[1] Univ Kansas, Dept Pharmaceut Chem, Lawrence, KS 66047 USA
[2] Inst Nucl Chem & Technol, PL-03195 Warsaw, Poland
来源：
NUKLEONIKA | 2000年 / 45卷 / 01期
关键词：
ESR; quantum-mechanical calculations; radiolysis; thiaproline;
D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Radicals formed by gamma -radiolysis of thiaproline (thiazolidine-4-carboxylic acid) amino acid and its derivatives in a frozen acidic aqueous solution at 77 K and by subsequent warming from 95 to 200 K have been studied by electron spin resonance (ESR). The experimental parameters of radical spectra were compared with those obtained by quantum-mechanical calculations on AM1 and PM3 semiempirical levels.
引用
收藏
页码：101 / 108
页数：8
相关论文
共 50 条
  • [31] RADIATION-INDUCED OXIDATION OF SULFHYDRYL MOLECULES IN AQUEOUS-SOLUTIONS - A COMPREHENSIVE REVIEW
    LAL, M
    RADIATION PHYSICS AND CHEMISTRY, 1994, 43 (06): : 595 - 611
  • [32] RADIATION-INDUCED OXIDATION OF 2-PROPANOL BY HYDROGEN PEROXIDE IN AQUEOUS SOLUTIONS
    BUCHILL, CE
    GINNS, IS
    CANADIAN JOURNAL OF CHEMISTRY, 1970, 48 (08): : 1232 - &
  • [33] RADIATION-INDUCED OXIDATION OF AQUEOUS-SOLUTIONS OF 2,5-DICHLOROHYDROQUINONE
    FELLOWS, TJ
    HUGHES, G
    INTERNATIONAL JOURNAL FOR RADIATION PHYSICS AND CHEMISTRY, 1973, 5 (02): : 207 - 212
  • [34] Radiation-induced reduction of quinoxalin-2-one derivatives in aqueous solutions
    Skotnicki, Konrad
    De la Fuente, Julio R.
    Canete, Alvaro
    Bobrowski, Krzysztof
    RADIATION PHYSICS AND CHEMISTRY, 2016, 124 : 91 - 98
  • [35] ELECTRON-SPIN-RESONANCE OF A RADIATION-INDUCED DEFECT IN ALPO4
    HOWE, JD
    KAPPERS, LA
    HALLIBURTON, LE
    ARMINGTON, AF
    BULLETIN OF THE AMERICAN PHYSICAL SOCIETY, 1981, 26 (03): : 235 - 235
  • [36] A spectrophotometric and chromatographic study on the products of radiation-induced oxidation of 3,5-dihydroxytoluene in aqueous solutions
    Revina, AA
    Larionov, OG
    Kochetova, MV
    Zimina, GM
    Zolotarevskii, VI
    El'-Registan, GI
    HIGH ENERGY CHEMISTRY, 2004, 38 (03) : 147 - 152
  • [37] A Spectrophotometric and Chromatographic Study on the Products of Radiation-induced Oxidation of 3,5-Dihydroxytoluene in Aqueous Solutions
    A. A. Revina
    O. G. Larionov
    M. V. Kochetova
    G. M. Zimina
    V. I. Zolotarevskii
    G. I. El'-Registan
    High Energy Chemistry, 2004, 38 : 147 - 153
  • [38] THE RADIATION-INDUCED OXIDATION AND REDUCTION OF GUANINE - ELECTRON-SPIN RESONANCE ELECTRON NUCLEAR DOUBLE-RESONANCE STUDIES OF IRRADIATED GUANOSINE CYCLIC MONOPHOSPHATE
    KIM, H
    BUDZINSKI, EE
    BOX, HC
    JOURNAL OF CHEMICAL PHYSICS, 1989, 90 (03): : 1448 - 1451
  • [39] AN ELECTRON SPIN RESONANCE STUDY OF RADIATION-INDUCED CENTERS OF CHEMICAL ACTIVITY IN A SILICA-ALUMINA GEL
    HENTZ, RR
    WICKENDE.DK
    JOURNAL OF PHYSICAL CHEMISTRY, 1969, 73 (04): : 817 - &
  • [40] ELECTRON-SPIN-RESONANCE STUDY OF RADIATION-INDUCED RADICALS IN AROMATIC AND ALIPHATIC AMINO ACIDS AND PEPTIDES
    CASTELEIJN, G
    DEPIREUX, J
    MULLER, A
    INTERNATIONAL JOURNAL OF RADIATION BIOLOGY AND RELATED STUDIES IN PHYSICS CHEMISTRY AND MEDICINE, 1964, 8 (02): : 157 - 164
12345