A MOF-derived Co-CoO@N-doped porous carbon for efficient tandem catalysis: dehydrogenation of ammonia borane and hydrogenation of nitro compounds

被引:177
|
作者
Ma, Xiao [1 ]
Zhou, Yu-Xiao [1 ]
Liu, Hang [1 ]
Li, Yang [1 ]
Jiang, Hai-Long [1 ]
机构
[1] Univ Sci & Technol China, Dept Chem, Collaborat Innovat Ctr Suzhou Nano Sci & Technol, Hefei Natl Lab Phys Sci Microscale,CAS Key Lab So, Hefei 230026, Anhui, Peoples R China
关键词
METAL-ORGANIC FRAMEWORKS; HIGH-SURFACE-AREA; STORAGE; NANOPARTICLES; GENERATION; NITROARENES; CONVERSION; HYDROLYSIS; REDUCTION;
D O I
10.1039/c6cc03149h
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The one-step pyrolysis of a zeolite-type metal-organic framework, Co(2-methylimidazole)(2) (ZIF-67), produces an N-doped porous carbon incorporating well-dispersed Co/CoO nanoparticles, which exhibit excellent catalytic activity, chemoselectivity and magnetic recyclability for the tandem dehydrogenation of ammonia borane and hydrogenation of nitro compounds at room temperature.
引用
收藏
页码:7719 / 7722
页数:4
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