Synthesis of Novel Substituted Phenanthrenes and Polycyclic Heteroarenes by Pd-Catalyzed, Direct, Intramolecular Arylation/Heteroarylation

被引:43
|
作者
Yadav, Ashok K. [1 ]
Ila, Hiriyakkanavar [1 ]
Junjappa, Hiriyakkanavar [1 ]
机构
[1] Indian Inst Technol, Dept Chem, Kanpur 208016, Uttar Pradesh, India
关键词
Cyclization; Heteroarenes; Palladium; Phenanthrenes; Polycycles; ALPHA-OXOKETENE DITHIOACETALS; HIGHLY REGIOSELECTIVE SYNTHESIS; TOPOISOMERASE-I; HETEROAROMATIC ANNULATION; COUPLING REACTIONS; DNA-BINDING; ARYLATION; PHOTOCYCLIZATION; COMBINATION; CARBAZOLES;
D O I
10.1002/ejoc.200901036
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A novel route to substituted phenanthrenes and polycyclic heteroarenes by direct, Pd-catalyzed, intramolecular arylation/heteroarylation of 2-(2-bromoaryl/heteroaryl)-3-(aryl/heteroaryl)-3-(methylthio)acrylonitriles has been reported.
引用
收藏
页码:338 / 344
页数:7
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