Tris(dimethylamino) phosphine Selenide Complexes of Cadmium(II): Synthesis and Multinuclear (31P, 77Se, and 113Cd) NMR Characterization in Solution

被引：2

作者：

Dhia, M. T. Ben ^{[1
]}

Sanhoury, M. A. M. K. ^{[1
]}

Zenati, C. ^{[1
]}

Khaddar, M. R. ^{[1
]}

机构：

[1] Univ Tunis El Manar, Fac Sci, Dept Chem, Lab Coordinat Chem, Tunis 1060, Tunisia

来源：

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 2009年 / 184卷 / 11期

关键词：

Cadmium complex; (2)J(P-Se) coupling; P-31; Se-77; and Cd-113 NMR; phosphine; selenide; COORDINATION; PROTEINS; SPECTROSCOPY; SULFIDES; LIGANDS; ENZYMES; C6H11; SE; E';

D O I：

10.1080/10426500802704183

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The complexes CdL4(ClO4)(2) (1), CdL2(NO3)(2) (2), and CdL2Cl2 (3) (L = (Me2N)(3)P(Se)) have been prepared and characterized by elemental analysis, conductivity measurements, IR, and multinuclear (P-31, Se-77, and Cd-113) NMR spectroscopy. P-31 and Se-77 NMR data were informative of changes associated with complex formation. The structure of the prepared complexes was further confirmed in solution by their Cd-113 NMR spectra, which show a quintuplet for the perchlorate complex and a triplet for each of the nitrate and chloride complexes due, respectively, to coupling with four and two equivalent phosphorus atoms, consistent with a four coordinate tetrahedral geometry for the cadmium center. The NMR data are discussed and compared with those reported for related complexes.

引用

页码：3082 / 3089

页数：8

共 46 条

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